Nitric acid, cobalt(2+)salt, hydrate (2:1:6)

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand CAS-No. : : : : Cobalt(II) nitrate hexahydrate 203106 Anonymous 10026-22-9 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Oxidizing solids (Category 2) Acute toxicity, Oral (Category 4) Respiratory sensitization (Category 1) Skin sensitization (Category 1) Germ cell mutagenicity (Category 2) Reproductive toxicity (Category 1B) Carcinogenicity, Inhalation (Category 1B) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC Contact with combustible material may cause fire. May cause cancer by inhalation. May impair fertility. Possible risk of irreversible effects. Harmful if swallowed. May cause sensitization by inhalation and skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H272 H302 Danger May intensify fire; oxidiser. Harmful if swallowed. H317 H334 H341 H350i H360 H410 Precautionary statement(s) P201 P220 P261 P273 P280 P308 + P313 Supplemental Hazard May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing genetic defects. May cause cancer by inhalation. May damage fertility or the unborn child. Very toxic to aquatic life with long lasting effects. Obtain special instructions before use. Keep/Store away from clothing/ combustible materials. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Avoid release to the environment. Wear protective gloves. IF exposed or concerned: Get medical advice/ attention. none Statements Restricted to professional users. According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R49 R60 R20 R8 R68 R42/43 R50/53 May cause cancer by inhalation. May impair fertility. Also harmful by inhalation. Contact with combustible material may cause fire. Possible risk of irreversible effects. May cause sensitization by inhalation and skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S53 S45 S60 S61 Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ Safety data sheets. Restricted to professional users. 2.3 3. 3.1 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Substances Synonyms Formula Molecular Weight Component : : : Cobaltous nitrate CoN2O6 · 6H2O 291,03 g/mol Concentration Cobaltous nitrate, hexahydrate Included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH) CAS-No. 10026-22-9 - 4. 4.1 4.2 4.3 5. 5.1 5.2 5.3 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture nitrogen oxides (NOx) Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking.Keep away from heat and sources of ignition. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 7.3 8. 8.1 8.2 9. 9.1 Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: Crystals with lumps Colour: red no data available no data available 4,0 at 100 g/l at 20 °C Melting point/range: 55 °C - lit. no data available not applicable no data available i) Flammability (solid, gas) no data available j) k) Upper/lower flammability or explosive limits Vapour pressure no data available no data available l) Vapour density no data available m) Relative density 1,88 g/cm3 n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties soluble no data available no data available no data available no data available no data available no data available 9.2 Other safety information Bulk density 8.000 kg/m3 10. 10.1 10.2 10.3 10.4 10.5 10.6 11. 11.1 STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid Heat. Exposure to moisture. Incompatible materials Organic materials, Reducing agents Hazardous decomposition products Other decomposition products - no data available TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat - 691 mg/kg LD50 Oral - rat - 434 mg/kg Remarks: anhydrous Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity In vitro tests showed mutagenic effects no data available Carcinogenicity Tumorigenic:Tumors at site or application. Possible human carcinogen IARC: IARC: 2B - Group 2B: Possibly carcinogenic to humans (Cobaltous nitrate, hexahydrate) 2A - Group 2A: Probably carcinogenic to humans (Cobaltous nitrate, hexahydrate) 2B - Group 2B: Possibly carcinogenic to humans (Cobaltous nitrate, hexahydrate) 2A - Group 2A: Probably carcinogenic to humans (Cobaltous nitrate, hexahydrate) Reproductive toxicity no data available Presumed human reproductive toxicant Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. May cause respiratory tract irritation. Harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: QU7355500 12. 12.1 12.2 12.3 12.4 12.5 12.6 13. 13.1 ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Very toxic to aquatic life. no data available DISPOSAL CONSIDERATIONS Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. 14. 14.1 TRANSPORT INFORMATION UN number 14.2 ADR/RID: 1477 UN proper shipping name IMDG: 1477 IATA: 1477 ADR/RID: IMDG: IATA: NITRATES, INORGANIC, N.O.S. NITRATES, INORGANIC, N.O.S. Nitrates, inorganic, n.o.s. 14.3 Transport hazard class(es) 14.4 14.5 14.6 15. ADR/RID: 5.1 Packaging group ADR/RID: II Environmental hazards ADR/RID: no Special precautions for user no data available REGULATORY INFORMATION IMDG: 5.1 IMDG: II IMDG Marine pollutant: no IATA: 5.1 IATA: II IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 15.2 16. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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