Benzeneacetic acid,4-chloro-a-(4-chlorophenyl)-a-hydroxy-, ethyl ester

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand Index-No. CAS-No. : : : : : Chlorobenzilate 45376 Fluka 607-159-00-0 510-15-6 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute toxicity, Oral (Category 4) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC Harmful if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H302 H410 Precautionary statement(s) P273 P501 Supplemental Hazard Statements Warning Harmful if swallowed. Very toxic to aquatic life with long lasting effects. Avoid release to the environment. Dispose of contents/ container to an approved waste disposal plant. none According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R22 R50/53 Harmful if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S60 S61 This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ Safety data sheets. 2.3 3. 3.1 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula Molecular Weight Component Chlorobenzilate : : C16H14Cl2O3 325,19 g/mol Concentration CAS-No. EC-No. Index-No. 510-15-6 208-110-2 607-159-00-0 - 4. 4.1 4.2 4.3 5. 5.1 5.2 5.3 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 8. 8.1 8.2 Further information no data available ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). 9. 9.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: solid no data available no data available no data available no data available 146 - 148 °C at 0,05 hPa no data available no data available i) Flammability (solid, gas) no data available j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density no data available no data available no data available m) Relative density 1,282 g/cm3 at 20 °C n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties insoluble log Pow: 4,74 no data available no data available no data available no data available no data available 9.2 10. 10.1 10.2 10.3 10.4 10.5 10.6 Other safety information no data available STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials no data available Hazardous decomposition products Other decomposition products - no data available 11. 11.1 TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat - 700 mg/kg LD50 Dermal - rabbit - > 1.000 mg/kg Skin corrosion/irritation Skin - rabbit - Open irritation test Serious eye damage/eye irritation Eyes - rabbit - Moderate eye irritation Respiratory or skin sensitization no data available Germ cell mutagenicity Genotoxicity in vitro - mouse - lymphocyte Mutation in mammalian somatic cells. Genotoxicity in vivo - rat - Oral Morphological transformation. Genotoxicity in vivo - mouse - Oral Other mutation test systems Carcinogenicity Carcinogenicity - rat - Oral Tumorigenic:Carcinogenic by RTECS criteria. Blood:Lymphomas including Hodgkin's disease. Skin and Appendages: Other: Tumors. Carcinogenicity - rat - Oral Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Liver:Tumors. Carcinogenicity - mouse - Oral Tumorigenic:Carcinogenic by RTECS criteria. Gastrointestinal:Tumors. Carcinogenicity - mouse - Oral Tumorigenic:Carcinogenic by RTECS criteria. Liver:Tumors. Blood:Lymphomas including Hodgkin's disease. IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Chlorobenzilate) Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes Additional Information RTECS: DD2275000 May be harmful if inhaled. May cause respiratory tract irritation. Harmful if swallowed. Harmful if absorbed through skin. May cause skin irritation. Causes serious eye irritation. 12. 12.1 ECOLOGICAL INFORMATION Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates LC50 - Oncorhynchus mykiss (rainbow trout) - 0,7 mg/l - 96,0 h EC50 - Daphnia pulex (Water flea) - 0,87 mg/l - 48 h 12.2 12.3 12.4 12.5 12.6 13. 13.1 14. 14.1 Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Very toxic to aquatic life with long lasting effects. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 ADR/RID: 3077 UN proper shipping name IMDG: 3077 IATA: 3077 ADR/RID: IMDG: IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Chlorobenzilate) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Chlorobenzilate) Environmentally hazardous substance, solid, n.o.s. (Chlorobenzilate) 14.3 Transport hazard class(es) 14.4 14.5 14.6 ADR/RID: 9 Packaging group ADR/RID: III Environmental hazards ADR/RID: yes Special precautions for user IMDG: 9 IMDG: III IMDG Marine pollutant: yes IATA: 9 IATA: III IATA: yes Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids. 15. 15.1 REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available 15.2 16. Chemical Safety Assessment no data available OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The informationin this document is based on the resent state of our knowledge and is applicable to the product with regard toappropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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