Chlorsulfuron

1.
1.1
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifiers
Product name
Product Number
Brand
Index-No.
CAS-No.
:
:
:
:
:
Chlorosulfuron
34322
Fluka
613-121-00-4
64902-72-3
1.2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
:
Laboratory chemicals, Manufacture of substances
2.
2.1
2.2
HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute aquatic toxicity (Category 1)
Chronic aquatic toxicity (Category 1)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word
Hazard statement(s)
H410
Precautionary statement(s)
P273
P501
Supplemental Hazard
Statements
Warning
Very toxic to aquatic life with long lasting effects.
Avoid release to the environment.
Dispose of contents/ container to an approved waste disposal plant.
none
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
S-phrase(s)
S60
S61
This material and its container must be disposed of as hazardous waste.
Avoid release to the environment. Refer to special instructions/ Safety
data sheets.
2.3
3.
3.1
Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula
Molecular Weight
Component
Chlorsulfuron
:
:
C12H12ClN5O4S
357,77 g/mol
Concentration
CAS-No.
EC-No.
Index-No.
64902-72-3
265-268-5
613-121-00-4
-
4.
4.1
4.2
4.3
5.
5.1
5.2
5.3
5.4
FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
no data available
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Hydrogen chloride gas
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE
Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end uses
no data available
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous
substances, and to the specific work-place., The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired,
use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9.
9.1
PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour Threshold
pH
Melting point/freezing
point
Initial boiling point and
boiling range
Flash point
Evaporation rate
Form: solid
no data available
no data available
no data available
no data available
no data available
no data available
no data available
i)
Flammability (solid, gas) no data available
j)
k)
l)
Upper/lower
flammability or
explosive limits
Vapour pressure
Vapour density
no data available
no data available
no data available
m) Relative density
no data available
n)
o)
p)
q)
r)
s)
t)
Water solubility
Partition coefficient: n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive properties
Oxidizing properties
no data available
no data available
no data available
no data available
no data available
no data available
no data available
9.2
10.
10.1
10.2
10.3
10.4
10.5
10.6
Other safety information
no data available
STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
no data available
Hazardous decomposition products
Other decomposition products - no data available
11.
11.1
TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 5.545 mg/kg
LC50 Inhalation - rat - 4 h - > 5.900 mg/m3
LD50 Dermal - rabbit - 3.400 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
Additional Information
RTECS: YS6640000
May be harmful if inhaled. May cause respiratory tract irritation.
May be harmful if swallowed.
May be harmful if absorbed through skin. May cause skin irritation.
May cause eye irritation.
12.
12.1
ECOLOGICAL INFORMATION
Toxicity
Toxicity to fish
Toxicity to daphnia and
other aquatic
invertebrates
Toxicity to algae
LC50 - Oncorhynchus mykiss (rainbow trout) - > 0,25 mg/l - 96,0 h
EC50 - Daphnia magna (Water flea) - 0,37 mg/l - 48 h
EC50 - Pseudokirchneriella subcapitata (green algae) - 0,13 mg/l - 96 h
Growth inhibition LOEC - Pseudokirchneriella subcapitata - 0,019 mg/l - 96 h
12.2
12.3
12.4
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
12.5
12.6
13.
13.1
14.
14.1
Results of PBT and vPvB assessment
no data available
Other adverse effects
Very toxic to aquatic life.
DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION
UN number
14.2
ADR/RID: 3077
UN proper shipping name
IMDG: 3077
IATA: 3077
ADR/RID:
IMDG:
IATA:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Chlorsulfuron)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Chlorsulfuron)
Environmentally hazardous substance, solid, n.o.s. (Chlorsulfuron)
14.3
Transport hazard class(es)
14.4
14.5
14.6
ADR/RID: 9
Packaging group
ADR/RID: III
Environmental hazards
ADR/RID: yes
Special precautions for user
IMDG: 9
IMDG: III
IMDG Marine pollutant: yes
IATA: 9
IATA: III
IATA: yes
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.
15.
15.1
15.2
16.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available
OTHER INFORMATION
Further information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

;

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COLORCOM LTD.

China (Mainland) Assessed Supplier

Chlorsulfuron

  • Assay:98%
  • Appearance:white crystal
  • Package:25/kg?paper?drum?and?double?plastic?food bags?inside.
  • Storage:Keep it in dry, cool and ventilated place
  • Transportation:By sea or by air
  • Application:Pharmaceutical intermediate
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LIDE PHARMACEUTICALS LIMITED

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Chlorsulfuron

  • Assay:99%,
  • Appearance:As per the typical COA
  • Package:1g/10g/100g/1kg/Export worthy packing; 25kg/drum
  • Storage:In well-closed container, protected from light and in cool & dry place.
  • Transportation:By Air, By Sea, By courier (door to door, DHL/FedEx/UPS/USPS)
  • Application:R&D and production for pharmaceuticals and chemicals
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Amadis Chemical Co., Ltd.

China (Mainland) Assessed Supplier

Amadis Chemical offer CAS#64902-72-3;CAT#A834916

  • Assay:97%
  • Appearance:Powder or liquid
  • Package:According to customer
  • Storage:Store in a tightly closed container, in a cool and dry place.
  • Transportation:Fedex,DHL,TNT,BY SEA and BY AIR
  • Application:Medicinal Chemistry Biomedicine Pharmaceutical intermediates Chemistry experiment Biological experiments Chemical reagent For R&D use only.
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Chemwill Asia Co., Ltd.

China (Mainland) Assessed Supplier

Chlorsulfuron

  • Assay:1,d,
  • Appearance:As per Certificate of analysis and our TDS, MSDS
  • Package:Export standard and according to the clients requirement
  • Storage:Store in dry, dark and ventilated place;ISO / Kosher /GMP licence commercial bulk capacity factory in China
  • Transportation:By AIR or by SEA GMP licence / US-FDA,South Korea-KFDA
  • Application:It is an important raw material and intermediate for chemical industry.
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HENAN NEW BLUE CHEMICAL CO.,LTD

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Chlorsulfuron

  • Assay:1,
  • Appearance:White powder
  • Package:25KGS/Drum
  • Storage:Room temperature
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