Benzene,1-chloro-4-nitro-

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand Index-No. CAS-No. : : : : : 1-Chloro-4-nitrobenzene C59122 610-005-00-5 100-00-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Carcinogenicity (Category 2) Germ cell mutagenicity (Category 2) Acute toxicity, Inhalation (Category 3) Acute toxicity, Dermal (Category 3) Acute toxicity, Oral (Category 3) Specific target organ toxicity - repeated exposure (Category 2) Chronic aquatic toxicity (Category 2) Classification according to EU Directives 67/548/EEC or 1999/45/EC Limited evidence of a carcinogenic effect. Possible risk of irreversible effects. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Toxic by inhalation, in contact with skin and if swallowed. Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H301 H311 - C59122 Danger Toxic if swallowed. Toxic in contact with skin. H331 H341 H351 H373 H411 Precautionary statement(s) P261 P273 P280 P301 + P310 P311 Supplemental Hazard Toxic if inhaled. Suspected of causing genetic defects. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Avoid release to the environment. Wear protective gloves/ protective clothing. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Call a POISON CENTER or doctor/ physician. none Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R23/24/25 R40 R48/20/21/22 R68 R51/53 Toxic by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of irreversible effects. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S28 S36/37 S45 S61 After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/ Safety data sheets. 2.3 3. 3.1 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula Molecular Weight Component 1-Chloro-4-nitrobenzene : : C6H4ClNO2 157,55 g/mol Concentration CAS-No. EC-No. Index-No. 100-00-5 202-809-6 610-005-00-5 - 4. 4.1 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. - C59122 In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 4.3 5. 5.1 5.2 5.3 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 8. 8.1 8.2 Most important symptoms and effects, both acute and delayed May cause cyanosis. Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx), Hydrogen chloride gas Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. - C59122 Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). 9. 9.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: crystalline Colour: light yellow no data available no data available no data available Melting point/range: 83 - 84 °C 242 °C at 1.013 hPa 124 °C - closed cup no data available i) Flammability (solid, gas) no data available j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density no data available no data available no data available m) Relative density 1,298 g/cm3 n) o) p) q) r) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity insoluble log Pow: 2,6 no data available no data available no data available - C59122 s) t) Explosive properties Oxidizing properties no data available no data available 9.2 10. 10.1 10.2 10.3 10.4 10.5 10.6 11. 11.1 Other safety information no data available STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents, Strong bases Hazardous decomposition products Other decomposition products - no data available TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat - 420 mg/kg Remarks: Behavioral:Somnolence (general depressed activity). Liver:Fatty liver degeneration. Blood:Methemoglobinemia-Carboxyhemoglobin. Skin corrosion/irritation Skin - rabbit - Mild skin irritation Serious eye damage/eye irritation Eyes - rabbit - No eye irritation Respiratory or skin sensitization no data available Germ cell mutagenicity Laboratory experiments have shown mutagenic effects. In vitro tests showed mutagenic effects Carcinogenicity This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. Limited evidence of carcinogenicity in animal studies IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (1-Chloro-4-nitrobenzene) 3 - Group 3: Not classifiable as to its carcinogenicity to humans (1-Chloro-4-nitrobenzene) Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure. - C59122 Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes Toxic if inhaled. May cause respiratory tract irritation. Toxic if swallowed. Toxic if absorbed through skin. May cause skin irritation. May cause eye irritation. Signs and Symptoms of Exposure May cause cyanosis. Additional Information RTECS: Not available 12. 12.1 ECOLOGICAL INFORMATION Toxicity Toxicity to daphnia and other aquatic invertebrates Toxicity to algae EC50 - Daphnia magna (Water flea) - 2,7 mg/l - 48 h Growth inhibition EC50 - Chlorella pyrenoidosa - 4,9 mg/l - 96 h 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d 12.3 Bioaccumulative potential Bioaccumulation Oncorhynchus mykiss (rainbow trout) - 36 d -0,780 μg/l Bioconcentration factor (BCF): 108 12.4 12.5 12.6 13. 13.1 14. 14.1 Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Toxic to aquatic life with long lasting effects. no data available DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 ADR/RID: 1578 UN proper shipping name IMDG: 1578 IATA: 1578 ADR/RID: IMDG: IATA: CHLORONITROBENZENES, SOLID CHLORONITROBENZENES, SOLID Chloronitrobenzenes, solid 14.3 Transport hazard class(es) ADR/RID: 6.1 - C59122 IMDG: 6.1 IATA: 6.1 14.4 Packaging group 14.5 14.6 15. ADR/RID: II Environmental hazards ADR/RID: yes Special precautions for user no data available REGULATORY INFORMATION IMDG: II IMDG Marine pollutant: yes IATA: II IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 15.2 16. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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