Card-20(22)-enolide,3,5,14-trihydroxy-19-oxo-, (3b,5b)-

1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING Product Name Strophanthidin 2.HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Acute toxicity, Inhalation (Category 1) Acute toxicity, Dermal (Category 2) Acute toxicity, Oral (Category 2) According to European Directive 67/548/EEC as amended. Very toxic by inhalation, in contact with skin and if swallowed. Label elements Pictogram Signal word Hazard statement(s) H300 H310 H330 Precautionary statement(s) P260 P264 P280 P284 P302 + P350 P310 Hazard symbol(s) T+ R-phrase(s) R26/27/28 S-phrase(s) S22 - S6626 Danger Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Wear protective gloves/protective clothing. Wear respiratory protection. IF ON SKIN: Gently wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/physician. Very toxic Very toxic by inhalation, in contact with skin and if swallowed. Do not breathe dust. S36/37/39 S45 Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Other hazards - none 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Formula Molecular Weight : : : 3β,5,14 -Trihydroxy-19-oxo- 5β,20(22) -cardenolide K-Strophanthidin Cymarigenen C23H32O6 404,50 g/mol CAS-No. EC-No. Index-No. Classification Concentration (3β,5β) -3,5,14-trihydroxy-19-oxocard-20(22)-enolide 66-28-4 200-626-6 - Acute Tox. 1; Acute Tox. 2; - H300, H310, H330 T+, R26/27/28 For the full text of the H-Statements mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Wear respiratory protection. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. - S6626 Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. Conditions for safe storage Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: -20 °C 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Eye protection Face shield and safety glasses Skin and body protection Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Safety data pH Melting point Boiling point Flash point Ignition temperature Lower explosion limit Upper explosion limit Water solubility solid no data available no data available no data available no data available no data available no data available no data available no data available 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid no data available Materials to avoid Strong oxidizing agents, Strong acids, Strong bases - S6626 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides 11. TOXICOLOGICAL INFORMATION Acute toxicity LD50 Intravenous - mouse - 0,33 mg/kg Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be fatal if inhaled. May cause respiratory tract irritation. May be fatal if swallowed. May cause skin irritation. May be fatal if absorbed through skin. May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: FH5425000 12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available PBT and vPvB assessment no data available Other adverse effects - S6626 no data available 13. DISPOSAL CONSIDERATIONS Product Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION ADR/RID UN-Number: 2811 Class: 6.1 Packing group: I Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. ( (3β,5β) -3,5,14-trihydroxy-19-oxocard-20(22)-enolide) IMDG UN-Number: 2811 Class: 6.1 Packing group: I EMS-No: F-A, S-A Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. ( (3β,5β )-3,5,14-trihydroxy-19-oxocard-20(22)-enolide) Marine pollutant: No IATA UN-Number: 2811 Class: 6.1 Packing group: I Proper shipping name: Toxic solid, organic, n.o.s. ( (3β,5β) -3,5,14-trihydroxy-19-oxocard-20(22)-enolide) 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox. H300 H310 H330 T+ R26/27/28 Acute toxicity Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Very toxic Very toxic by inhalation, in contact with skin and if swallowed. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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