METHACRYLIC ACID, polymer with ETHYL ACRYLATE

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand : : : Kollicoat? MAE 30 DP 42385 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute toxicity, Inhalation (Category 2) Chronic aquatic toxicity (Category 4) Classification according to EU Directives 67/548/EEC or 1999/45/EC Harmful by inhalation. May cause long-term adverse effects in the aquatic environment. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H330 H413 Precautionary statement(s) P260 P284 P310 Supplemental Hazard Statements - 42385 Danger Fatal if inhaled. May cause long lasting harmful effects to aquatic life. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wear respiratory protection. Immediately call a POISON CENTER or doctor/ physician. none According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R20 R53 S-phrase(s) Harmful by inhalation. May cause long-term adverse effects in the aquatic environment. none 2.3 3. 3.2 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Mixtures Synonyms : Methacrylic acid copolymer dispersion Methacrylic acid-ethyl acrylate copolymer (1:1) dispersion 30 % Component Classification Concentration 2-Propenoic acid, 2-methyl-, polymer with ethyl 2-propenoate CAS-No. 25212-88-8 Acute Tox. 2; Aquatic Chronic 25 - 50 % 4; H330, H413 Xn, R20 - R53 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 4. 4.1 4.2 4.3 5. 5.1 5.2 5.3 5.4 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available - 42385 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 8. 8.1 8.2 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Do not freeze. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). - 42385 9. 9.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: liquid Colour: milky, white very faint no data available 2,1 - 3 Melting point/range: < 0 °C Freezing point: 22 - 30 °C ca.100 °C at 1,013 hPa not applicable no data available i) Flammability (solid, gas) no data available j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density no data available no data available no data available m) Relative density 1,06 - 1,07 g/cm3 at 20 °C n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties completely miscible no data available does not ignite no data available no data available no data available no data available 9.2 10. 10.1 10.2 10.3 10.4 10.5 10.6 Other safety information no data available STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available - 42385 11. 11.1 TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat - > 2.000 mg/kg LC50 Inhalation - rat - 4 h - 1,03 mg/l Skin corrosion/irritation Skin - rabbit - No skin irritation - OECD Test Guideline 404 Serious eye damage/eye irritation No eye irritation Respiratory or skin sensitization Buehler Test - guinea pig - Did not cause sensitization on laboratory animals. - OECD Test Guideline 406 - Did not cause sensitization on laboratory animals. Germ cell mutagenicity Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be fatal if inhaled. May cause respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: Not available 12. 12.1 ECOLOGICAL INFORMATION Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae LC50 - other fish - > 100 mg/l - 96 h Method: OECD Test Guideline 203 EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h Method: OECD Test Guideline 202 EC50 - Algae - > 100 mg/l - 72 h Method: OECD Test Guideline 201 12.2 Persistence and degradability Biodegradability - 42385 aerobic - Exposure time 28 d Result: < 10 % - Not readily biodegradable. Method: OECD Test Guideline 302 12.3 12.4 12.5 12.6 13. 13.1 14. 14.1 Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 14.3 14.4 14.5 14.6 15. ADR/RID: - UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods Transport hazard class(es) ADR/RID: - Packaging group ADR/RID: - Environmental hazards ADR/RID: no Special precautions for user no data available REGULATORY INFORMATION IMDG: - IMDG: - IMDG: - IMDG Marine pollutant: no IATA: - IATA: - IATA: - IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 15.2 16. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox. Aquatic Chronic H330 H413 Xn R20 R53 - 42385 Acute toxicity Chronic aquatic toxicity Fatal if inhaled. May cause long lasting harmful effects to aquatic life. Harmful Harmful by inhalation. May cause long-term adverse effects in the aquatic environment. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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