Sulfuric acid,nickel(2+) salt (1:1), hydrate (8CI,9CI)

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand Index-No. CAS-No. : : : : : Nickel(II) sulfate hexa-/ heptahydrate 13635 028-009-00-5 15244-37-8 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Carcinogenicity, Inhalation (Category 1A) Acute toxicity, Inhalation (Category 4) Acute toxicity, Oral (Category 4) Skin sensitization (Category 1) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Reproductive toxicity (Category 1B) Germ cell mutagenicity (Category 2) Specific target organ toxicity - repeated exposure (Category 1) Skin irritation (Category 2) Respiratory sensitization (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC May cause cancer by inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause sensitization by inhalation and skin contact. Harmful by inhalation and if swallowed. May cause harm to the unborn child. Possible risk of irreversible effects. Toxic: danger of serious damage to health by prolonged exposure through inhalation. Irritating to skin. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram - 13635 Signal word Hazard statement(s) H302 H315 H317 H332 H334 H341 H350i H360D H372 H410 Precautionary statement(s) P201 P261 P273 P280 P308 + P313 P501 Supplemental Hazard Danger Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing genetic defects. May cause cancer by inhalation. May damage the unborn child. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. Obtain special instructions before use. Avoid breathing dust. Avoid release to the environment. Wear protective gloves. IF exposed or concerned: Get medical advice/ attention. Dispose of contents/ container to an approved waste disposal plant. none Statements Restricted to professional users. According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R49 R61 R20/22 R48/23 R38 R68 R42/43 R50/53 May cause cancer by inhalation. May cause harm to the unborn child. Also harmful by inhalation and if swallowed. Also toxic: danger of serious damage to health by prolonged exposure through inhalation. Irritating to skin. Possible risk of irreversible effects. May cause sensitization by inhalation and skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S53 S45 S60 S61 Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ Safety data sheets. Restricted to professional users. 2.3 3. 3.1 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula Molecular Weight Component : : NiSO4·6-7H2O 154,8 g/mol Concentration Nickel sulphate hexa-/heptahydrate CAS-No. 15244-37-8 - - 13635 EC-No. 232-104-9 Index-No. 028-009-00-5 4. 4.1 4.2 4.3 5. 5.1 5.2 5.3 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special hazards arising from the substance or mixture Nickel/nickel oxides, Sulphur oxides Nature of decomposition products not known. Sulphur oxides, Nickel/nickel oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information The product itself does not burn. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Avoid exposure - obtain special instructions before use. Provide appropriate exhaust ventilation at places where dust is formed. - 13635 7.2 7.3 8. 8.1 8.2 9. 9.1 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: crystalline Colour: green no data available no data available 4,5 no data available no data available not applicable no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available - 13635 k) l) Vapour pressure Vapour density no data available no data available m) Relative density 1,950 g/cm3 at 20 °C n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties no data available no data available no data available no data available no data available no data available no data available 9.2 Other safety information Bulk density 1.200 g/l 10. 10.1 10.2 10.3 10.4 10.5 10.6 11. 11.1 STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available May cause allergic respiratory and skin reactions Germ cell mutagenicity no data available Carcinogenicity This is or contains a component that has been reported to be carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA classification. Limited evidence of carcinogenicity in animal studies - 13635 IARC: 1 - Group 1: Carcinogenic to humans (Nickel sulphate hexa-/heptahydrate) Reproductive toxicity Presumed human reproductive toxicant Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure Inhalation - Causes damage to organs through prolonged or repeated exposure. Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Additional Information RTECS: Not available Toxic if inhaled. Causes respiratory tract irritation. Toxic if swallowed. Toxic if absorbed through skin. Causes skin irritation. 12. 12.1 ECOLOGICAL INFORMATION Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates LC50 - Oncorhynchus mykiss (rainbow trout) - 1,2 - 3,2 mg/l - 96,0 h EC50 - Daphnia magna (Water flea) - 2 mg/l - 48 h 12.2 12.3 12.4 12.5 12.6 13. 13.1 14. 14.1 Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Very toxic to aquatic life. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 ADR/RID: 3077 UN proper shipping name IMDG: 3077 IATA: 3077 ADR/RID: IMDG: IATA: - 13635 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Nickel sulphate hexa- /heptahydrate) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Nickel sulphate hexa- /heptahydrate) Environmentally hazardous substance, solid, n.o.s. (Nickel sulphate hexa-/heptahydrate) 14.3 Transport hazard class(es) 14.4 14.5 14.6 ADR/RID: 9 Packaging group ADR/RID: III Environmental hazards ADR/RID: yes Special precautions for user IMDG: 9 IMDG: III IMDG Marine pollutant: yes IATA: 9 IATA: III IATA: yes Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids. 15. 15.1 15.2 16. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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