CasNo.87413-09-0,Dess-Martin,(87413-09-0) Suppliers

1 Gram	Negotiable

Min.Order :1 Gram
Purity: >98%
Payment Terms : L/C,MoneyGram,Other

Keywords

87413-09-0 Dess-Martin periodinane 98%Dess-Martin periodinane

Quick Details

Appearance:as description
Application:Pharmaceutical intermediates
PackAge:5g, 10g, 50g, 100g, 1kg
ProductionCapacity:1|Metric Ton|Day
Storage:Store in dry, dark and ventilated place
Transportation:by air or courier

Superiority:

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Details:

Dess-Martin periodinane
CAS No.:	87413-09-0
Synonyms:	(1,1-diacetyloxy-3-oxo-1λ<sup>5</sup>,2-benziodoxol-1-yl) acetate;
Formula:	C13H13IO8
Exact Mass:	423.96600
Molecular Weight:	424.14200
PSA:	105.20000
LogP:	1.95370

DescriptionFeedback

Dess–Martin periodinane (DMP) is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. This periodinane has several advantages over chromium- and DMSO-based oxidants that include milder conditions (room temperature, neutral pH), shorter reaction times, higher yields, simplified workups, high chemoselectivity, tolerance of sensitive functional groups, and a long shelf life. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the reagent in 1983. It is based on IBX, but due to the acetate groups attached to the central iodine atom, DMP is much more reactive than IBX and is much more soluble in organic solvents.

PropertiesFeedback
Appearance & Physical State:	white crystalline powder
Density:	1.362
Melting Point:	130-133ºC
Boiling Point:	40ºC
Flash Point:	>221 °F
Storage Condition:	0-6ºC

Safety InfoFeedback
Symbol:	GHS03 GHS07
Sign:	Warning
hazard declaration:	H272; H302 + H312 + H332; H315; H319; H335
hazard declaration add:	Risk of explosion if heated under confinement.
waring notice:	P220; P261; P280; P305 + P351 + P338
Safety Statements:	S17-S23-S24/25-S36/37
WGK Germany:	3
RIDADR:	UN 1593 6
Risk Statements:	R40; R8
Hazard Codes:	Xn