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Trimethylsilyl trifluoromethanesulfonate SILANE TMS-TRIFLATE;TMSOTF;TMS TRIFLATE;TRIMETHYLSILYL TRIFLATE;TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE;TRIMETHYLSILYL TRIFLUOROMETHANESULPHONATE;TRIMETHYLSILYL TRIFLUOROMETHYLSULFONATE;TRIMETHYLSILY 27607-77-8
Product Name: | Trimethylsilyl trifluoromethanesulfonate |
Synonyms: | SILANE TMS-TRIFLATE;TMSOTF;TMS TRIFLATE;TRIMETHYLSILYL TRIFLATE;TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE;TRIMETHYLSILYL TRIFLUOROMETHANESULPHONATE;TRIMETHYLSILYL TRIFLUOROMETHYLSULFONATE;TRIMETHYLSILYL TRIFLUOROMETHYLSULPHONATE |
CAS: | 27607-77-8 |
MF: | C4H9F3O3SSi |
MW: | 222.26 |
EINECS: | 248-565-4 |
Product Categories: | straight chain compounds;Small molecule;Biochemistry;Nucleosides, Nucleotides & Related Reagents;Protecting Agents for Hydroxyl and Amino Groups;Protecting Agents, Phosphorylating Agents & Condensing Agents;Protection & Derivatization Reagents (for Synthesis);Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Silyl Esters;Si-O Compounds;Synthetic Organic Chemistry;metal triflate compounds;Cationic initiator |
Mol File: | 27607-77-8.mol |
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Trimethylsilyl trifluoromethanesulfonate Chemical Properties |
bp | 77 °C80 mm Hg(lit.) |
density | 1.228 g/mL at 25 °C(lit.) |
refractive index | n20/D 1.36(lit.) |
Fp | 78 °F |
storage temp. | 2-8°C |
Water Solubility | REACTS |
Sensitive | Moisture Sensitive |
Merck | 14,9719 |
BRN | 1868911 |
CAS DataBase Reference | 27607-77-8(CAS DataBase Reference) |
NIST Chemistry Reference | Trimethylsilyl trifluoromethanesulfonate(27607-77-8) |
EPA Substance Registry System | Methanesulfonic acid, trifluoro-, trimethylsilyl ester(27607-77-8) |
Safety Information |
Hazard Codes | C,F |
Risk Statements | 10-14-34 |
Safety Statements | 16-26-36/37/39-45-8 |
RIDADR | UN 2920 8/PG 2 |
WGK Germany | 3 |
F | 10-21 |
Hazard Note | Corrosive/Flammable |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | III |
HS Code | 29310095 |
MSDS Information |
Provider | Language |
---|---|
Trimethylsilyl triflate | English |
ACROS | English |
SigmaAldrich | English |
ALFA | English |
Trimethylsilyl trifluoromethanesulfonate Usage And Synthesis |
Chemical Properties | clear colourless to light brown fuming liquid |
Usage | Trimethylsilyl Trifluoromethanesulfonate is a trialkylsilyl triflate used as a catalyst in organic synthesis. Trimethylsilyl Trifluoromethanesulfonate is used in combination with boron trifluoride eth yl ether to prepare a Lewis acid that is more powerful than its components and especially effective in acetonitrile solvent. Trimethylsilyl is a common reagent used in a Dieckmann-like cyclization of ester-imides and diesters. |
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