(Diacetoxyiodo)benzene
3240-34-4
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(Diacetoxyiodo)benzene Basic information |
Product Name: | (Diacetoxyiodo)benzene |
Synonyms: | PHENYLIODINE DIACETATE;PIA;AURORA KA-6690;(DIACETOXYIODO)BENZENE;DIACETOXYIODOSOBENZENE;DAIB;LABOTEST-BB LT00847235;IODOBENZENE I,I-DIACETATE |
CAS: | 3240-34-4 |
MF: | C10H11IO4 |
MW: | 322.1 |
EINECS: | 221-808-1 |
Product Categories: | Benzene derivatives;APIs;Hypervalent Iodine Compounds;Oxidation;Synthetic Organic Chemistry |
Mol File: | 3240-34-4.mol |
(Diacetoxyiodo)benzene Chemical Properties |
mp | 161-163 °C(lit.) |
solubility | INSOLUBLE |
Water Solubility | INSOLUBLE |
Sensitive | Light Sensitive |
BRN | 1879369 |
CAS DataBase Reference | 3240-34-4(CAS DataBase Reference) |
NIST Chemistry Reference | Iodobenzene diacetate(3240-34-4) |
EPA Substance Registry System | Iodine, bis(acetato-.kappa.O)phenyl- (3240-34-4) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 22-24/25-37/39-26-36/37/39-27 |
RIDADR | 1479 |
WGK Germany | 3 |
RTECS | DA3525000 |
F | 4.10-8 |
Hazard Note | Irritant |
HazardClass | 6.1(b) |
PackingGroup | III |
HS Code | 29310095 |
(Diacetoxyiodo)benzene Usage And Synthesis |
Chemical Properties | white to light yellow crystal powder |
Usage | (Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic a cid into the corresponding aldehydes, ketones and nitriles. |
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