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994-30-9 Chlorotriethylsilane TRIETHYLSILYL CHLORIDE
Synonyms: CHLOROTRIETHYLSILANE;SILANE E3;TESCI;TESCL;chlorotriethyl-silan;CT2520;TRIETHYLCHLOROSILANE;TRIETHYLSILYL CHLORIDE
CAS: 994-30-9
MF: C6H15ClSi
MW: 150.72
EINECS: 213-615-6
Product Categories: Other Reagents;Monochlorosilanes;Protection & Derivatization Reagents (for Synthesis);Si (Classes of Silicon Compounds);Si-Cl Compounds;Synthetic Organic Chemistry;Blocking Agents;Chloro Silanes;Protective Agents;Silylating Agents;Chemistry;organosilicon compounds;Organics
Mol File: 994-30-9.mol
Chlorotriethylsilane Structure
Chlorotriethylsilane Chemical Properties
Melting point -50°C
Boiling point 142-144 °C(lit.)
density 0.898 g/mL at 25 °C(lit.)
refractive index n20/D 1.43(lit.)
Fp 85 °F
storage temp. Flammables area
solubility Soluble in aprotic organic solvents.
Sensitive Moisture Sensitive
BRN 1732860
CAS DataBase Reference 994-30-9(CAS DataBase Reference)
NIST Chemistry Reference Silane, chlorotriethyl-(994-30-9)
EPA Substance Registry System Silane, chlorotriethyl-(994-30-9)
Safety Information
Hazard Codes C,F
Risk Statements 11-14-19-35-34-10-22-36/37-40-37
Safety Statements 26-36/37/39-43-45-25-16-33
RIDADR UN 2986 8/PG 2
WGK Germany 1
F 10-21
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29310095
【Synonyms】
Triethylchlorosilane
【CAS】
994-30-9
【Formula】
C6H15ClSi
【Molecular Weight】
150.72999999999999
【EINECS】
213-615-6
【Beilstein/Gmelin】
1732860
【Beilstein Reference】
4-04-00-04051
【EC Class】
flammable, corrosive
Physical and Chemical Properties Back to Contents
【Appearance】
Clear, colorless liquid.
【Solubility in water】
Decomposition
【Boiling Point】
144
【Density】
0.9249 g/cm3 (0 C)
【Refractive Index】
1.4314 (20 C)
First Aid Measures Back to Contents
【Ingestion】
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Skin】
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】
Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and Storage Back to Contents
【Storage】
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Handling】
Wash thoroughly after handling. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards Identification Back to Contents
【Ingestion】
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
【Inhalation】
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
【Skin】
Causes skin burns.
【Eyes】
Causes eye burns.
【Hazards】
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】
R 10 14 34
【EC Safety Phrase】
S 16 26 36/37/39 45
【UN (DOT)】
2920
Exposure Controls/Personal Protection Back to Contents
【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting Measures Back to Contents
【Flash Point】
30
【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
【Fire Potential】
Flammable/combustible material. May be ignited by heat, sparks or flames.
Accidental Release Measures Back to Contents
【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. A vapor suppressing foam may be used to reduce vapors.
Stability and Reactivity Back to Contents
【Disposal Code】
24
【Stability】
Stable under normal temperatures and pressures.
【Incompatibilities】
Strong oxidizing agents.
【Decomposition】
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, silicon oxide.
【Combustion Products】
Fire will produce irritating, corrosive and/or toxic gases.
Transport Information Back to Contents
【UN Number】
2920
【Hazard Class】
8
【Packing Group】
I; II
【HS Code】
2931 00 95
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