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148-53-8 3-Methoxysalicylaldehyde 2-hydroxy-3-methoxy-benzaldehyde
3-Methoxysalicylaldehyde Basic information
Product Name: 3-Methoxysalicylaldehyde
Synonyms: TIMTEC-BB SBB000109;2-hydroxy-3-methoxy-benzaldehyd;2-hydroxy-m-anisaldehyd;6-Formyl-2-methoxyphenol;6-Formylguaiacol;m-Anisaldehyde, 2-hydroxy-;Ortho vanillin;Orthovanilline
CAS: 148-53-8
MF: C8H8O3
MW: 152.15
EINECS: 205-715-3
Product Categories: Aromatic Aldehydes & Derivatives (substituted);Aromatics;Aldehydes;Building Blocks;C8;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File: 148-53-8.mol
mp 40-42 °C(lit.)
bp 265-266 °C(lit.)
Fp >230 °F
Water Solubility slightly soluble
Sensitive Air Sensitive
BRN 471913
CAS DataBase Reference 148-53-8(CAS DataBase Reference)
NIST Chemistry Reference Benzaldehyde, 2-hydroxy-3-methoxy-(148-53-8)
EPA Substance Registry System Benzaldehyde, 2-hydroxy-3-methoxy-(148-53-8)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-36/37/38
Safety Statements 23-36-24/25-36/37/39-27-26
WGK Germany 3
RTECS CU6530000
F 10-23
HS Code 29124900
【Product Name】
3-Methoxysalicylaldehyde
【Synonyms】
2-Hydroxy-3-methoxybenzaldehyde
2-Hydroxy-m-anisaldehyde
3-Methoxy-2-hydroxybenzaldehyde
3-Methoxysalicylaldehyde
6-Formyl-2-methoxyphenol
6-Formylguaiacol
【CAS】
148-53-8
【Formula】
C8H8O3
【Molecular Weight】
152.15
【EINECS】
205-715-3
【RTECS】
CU6530000
【RTECS Class】
Mutagen; Primary Irritant
【Beilstein/Gmelin】
471913
【Beilstein Reference】
4-08-00-01747
Physical and Chemical Properties Back to Contents
【Appearance】
Yellow crystalline powder.
【Solubility in water】
Slightly soluble
【Melting Point】
40 - 42
【Boiling Point】
265
【Vapor Pressure】
0.0056 (25 C)
【Density】
1.2039 g/cm3 (45 C)
【pKa/pKb】
8.17 (pKa)
【Partition Coefficient】
1.4
【Heat Of Vaporization】
52.3 kJ/mol
【Heat Of Combustion】
-3829 kJ/mol
【Usage】
Used in the study of mutagenesis and as a synthetic precursor for pharmaceuticals.
【Vapor Density】
5.2
【Refractive Index】
1.5632 (45 C)
First Aid Measures Back to Contents
【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and Storage Back to Contents
【Storage】
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
【Handling】
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.
Hazards Identification Back to Contents
【Ingestion】
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
【Inhalation】
Causes respiratory tract irritation.
【Skin】
Causes skin irritation.
【Eyes】
Causes eye irritation.
【EC Risk Phrase】
R 22 36/37/38
【EC Safety Phrase】
S 26 36/37/39
Exposure Controls/Personal Protection Back to Contents
【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure.
【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Fire Fighting Measures Back to Contents
【Flash Point】
94
【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Accidental Release Measures Back to Contents
【Small spills/leaks】
Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity Back to Contents
【Stability】
Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】
Strong oxidizing agents.
【Decomposition】
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Transport Information Back to Contents
【HS Code】
2912 49 00
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