CasNo.135410-20-7,Acetamiprid 96% 97% TECH CAS NO.: 135410-20-7,(135410-20-7) Suppliers

1 Kilogram	Negotiable

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Purity: 96% 97%
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Keywords

acetamiprid insecticide (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylaceta Acetamiprid 96% 97% TC insecticide

Quick Details

Appearance:white powder
Application:control many kinds of pests, such as vegetable-moth, thistle, aphid on vegetables; thistle, peach fruit moth, powdery scale on fruit tree and tealeaf hopper, leek leaf miner.
PackAge: 25kg bag, drum
ProductionCapacity:1000|Metric Ton|Year
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neonicotinoid insecticide
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Insecticide neonicotinoid NOMENCLATURE Common name acetamiprid (pa ISO) IUPAC name (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine Chemical Abstracts name (E)-N-[(6-chloro-3-pyridinyl)methyl]-N'-cyano-N-methylethanimidamide CAS RN [135410-20-7] Development codes NI-25 (Nippon Soda) PHYSICAL CHEMISTRY Mol. wt. 222.7 M.f. C10H11ClN4 Form Colourless crystals. M.p. 98.9 °C V.p. <1 × 10-3 mPa (25 ºC) KOW logP = 0.80 (25 ºC) Henry <5.3 × 10-8 Pa m3 mol-1 (calc.) S.g./density 1.330 (20 °C) Solubility In water 4250 mg/l (25 ºC). Soluble in acetone, methanol, ethanol, dichloromethane, chloroform, acetonitrile and tetrahydrofuran. Stability Stable in buffered solutions at pH 4, 5, 7. Degraded slowly at pH 9 and 45 ºC. Stable under sunlight. pKa 0.7, v. weak base APPLICATIONS Biochemistry Agonist of the nicotinic acetylcholine receptor, affecting the synapses in the insect central nervous system. Mode of action Systemic insecticide with translaminar activity and with contact and stomach action. Uses Control of Hemiptera, especially aphids, Thysanoptera and Lepidoptera, by soil and foliar application, on a wide range of crops, especially vegetables, fruit and tea. Applied at 75-300 g/ha on vegetables, 100-700 g/ha in orchards. Formulation types FU; GR; EC; WP. ANALYSIS Tech. product by hplc; residues by gc. MAMMALIAN TOXICOLOGY Oral Acute oral LD50 for male rats 217, female rats 146, male mice 198, female mice 184 mg/kg. Skin and eye Acute percutaneous LD50 for male and female rats >2000 mg/kg. Non-irritating to skin and eyes (rabbits); not a skin sensitiser (guinea pigs). Inhalation LC50 (4 h) for male and female rats >0.29 mg/l. NOEL (2 y) for rats 7.1 mg/kg b.w.; (18 mo) for mice 20.3 mg/kg b.w.; (1 y) for dogs 20 mg/kg b.w. Other Negative in the Ames test. ECOTOXICOLOGY Birds LD50 for bobwhite quail 180 mg/kg. LC50 for bobwhite quail >5000 ppm. Fish LC50 (24-96 h) for carp >100 mg/l. Daphnia LC50 (24 h) >200 mg/l. Algae EC50 (72 h) >98.3 mg/l; NOEC (72 h) 98.3 mg/l. ENVIRONMENTAL FATE Plants Slowly degraded on or in plants, forming five identified metabolites (H. Saito et al., Proc. 9th IUPAC Int. Congr. Pestic. Chem., London, 1998, 2, 5A-010). Soil/Environment DT50 in clay loam 1 d; in light clay 1-2 d. DT50 for total residues 15-30 d.

Insecticide
neonicotinoid

NOMENCLATURE
Common name acetamiprid (pa ISO)
IUPAC name (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine
Chemical Abstracts name (E)-N-[(6-chloro-3-pyridinyl)methyl]-N'-cyano-N-methylethanimidamide
CAS RN [135410-20-7] Development codes NI-25 (Nippon Soda)

PHYSICAL CHEMISTRY
Mol. wt. 222.7 M.f. C10H11ClN4 Form Colourless crystals. M.p. 98.9 °C V.p. <1 × 10-3 mPa (25 ºC) KOW logP = 0.80 (25 ºC) Henry <5.3 × 10-8 Pa m3 mol-1 (calc.) S.g./density 1.330 (20 °C) Solubility In water 4250 mg/l (25 ºC). Soluble in acetone, methanol, ethanol, dichloromethane, chloroform, acetonitrile and tetrahydrofuran. Stability Stable in buffered solutions at pH 4, 5, 7. Degraded slowly at pH 9 and 45 ºC. Stable under sunlight. pKa 0.7, v. weak base

APPLICATIONS
Biochemistry Agonist of the nicotinic acetylcholine receptor, affecting the synapses in the insect central nervous system. Mode of action Systemic insecticide with translaminar activity and with contact and stomach action. Uses Control of Hemiptera, especially aphids, Thysanoptera and Lepidoptera, by soil and foliar application, on a wide range of crops, especially vegetables, fruit and tea. Applied at 75-300 g/ha on vegetables, 100-700 g/ha in orchards. Formulation types FU; GR; EC; WP.

ANALYSIS
Tech. product by hplc; residues by gc.

MAMMALIAN TOXICOLOGY
Oral Acute oral LD50 for male rats 217, female rats 146, male mice 198, female mice 184 mg/kg.  Skin and eye Acute percutaneous LD50 for male and female rats >2000 mg/kg. Non-irritating to skin and eyes (rabbits); not a skin sensitiser (guinea pigs).  Inhalation LC50 (4 h) for male and female rats >0.29 mg/l.  NOEL (2 y) for rats 7.1 mg/kg b.w.; (18 mo) for mice 20.3 mg/kg b.w.; (1 y) for dogs 20 mg/kg b.w.  Other Negative in the Ames test.

ECOTOXICOLOGY
Birds LD50 for bobwhite quail 180 mg/kg. LC50 for bobwhite quail >5000 ppm.  Fish LC50 (24-96 h) for carp >100 mg/l.  Daphnia LC50 (24 h) >200 mg/l.  Algae EC50 (72 h) >98.3 mg/l; NOEC (72 h) 98.3 mg/l.

ENVIRONMENTAL FATE
Plants Slowly degraded on or in plants, forming five identified metabolites (H. Saito et al., Proc. 9th IUPAC Int. Congr. Pestic. Chem., London, 1998, 2, 5A-010).  Soil/Environment DT50 in clay loam 1 d; in light clay 1-2 d. DT50 for total residues 15-30 d.