Superiority:
Product Name: 2,5-Dimethyl pyrazine
Synonyms: 2,5-Dimethylpyrazine 98+%;2,5-Dimethylprazin;2,5-Dimethylpyrazine (contains 2,6-isomer);2,5-DIMETHYL PYRAZINE, NATURAL;2,5-Dimethylpyrazine,99%;2,5-Dimethylpyrazine, Research grade;2,5-Dimethyl pyrazine >=99.0%;5-diMethyl pyrazine
CAS: 123-32-0
MF: C6H8N2
MW: 108.14
EINECS: 204-618-3
Product Categories: -;Pyrazine;Heterocyclic Compounds;Acipimox;Mono- & Polyalkylpyrazines;pyrazine Flavor;Building Blocks;Heterocyclic Building Blocks;Alphabetical Listings;C-D;Flavors and Fragrances;Pyrazine compounds;Pyrazines
Mol File: 123-32-0.mol
2,5-Dimethyl pyrazine Structure
2,5-Dimethyl pyrazine Chemical Properties
Melting point 15°C
Boiling point 155 °C(lit.)
density 0.99 g/mL at 25 °C(lit.)
refractive index n20/D 1.502(lit.)
FEMA 3272 | 2,5-DIMETHYLPYRAZINE
Fp 147 °F
storage temp. Store below +30°C.
form Liquid
Specific Gravity 0.990
color Clear colorless to pale yellow
PH 7 (H2O)
Sensitive Hygroscopic
JECFA Number 766
BRN 107052
CAS DataBase Reference 123-32-0(CAS DataBase Reference)
NIST Chemistry Reference Pyrazine, 2,5-dimethyl-(123-32-0)
EPA Substance Registry System Pyrazine, 2,5-dimethyl-(123-32-0)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-36/37/38-R22
Safety Statements 26-36
RIDADR NA 1993 / PGIII
WGK Germany 3
RTECS UQ2800000
Hazard Note Irritant
TSCA Yes
HS Code 29339990
MSDS Information
Provider Language
2,5-Dimethyl pyrazine English
SigmaAldrich English
ACROS English
ALFA English
2,5-Dimethyl pyrazine Usage And Synthesis
Chemical Properties clear colorless to pale yellow liquid
Chemical Properties 2,5-Dimethylpyrazine has a characteristic odor of earthy, potato-like odor.
Occurrence Reported to be present in bakery products, roasted barley, cocoa products, roasted coffee, dairy products, pork, peanuts, pecans, filberts, popcorn, potato products, rum and whiskey, soy products; a volatile component in roasted filberts and in potato chips; reportedly identified in the fat of cooked beef; also reported found in toasted off-flavors. Also reported in cheeses, butter, boiled eggs, grilled beef, tea, barley, oats, oatmeal, soybeans, heated beans, kohlrabi, shrimp and mushrooms. Also reported found in coffee, potato chips and shrimp
Uses 2,5-Dimethyl pyrazine is used for blending food, nuts and beverage flavors.
Preparation By the interaction of acrolein and ammonia when heated in glycerol in the presence of ammonium salts; by self-condensation of aminoacetone, followed by oxidation with mercury chloride.
Aroma threshold values Detection: 80 ppb to 1.8 ppm
Taste threshold values Taste characteristics at 7.5 ppm: musty, potato, cocoa and nutty with a fatty and oily nuance
Safety Profile Moderately toxic by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx
Purification Methods Purify it via its picrate (m 150o) which is decomposed with a base (e,g, KOH) and distilled. [Wiggins and Wise J Chem Soc 4780 1956]. [Beilstein 23/5 V 403.]
Details:
Safety Statements:26-36
HS Code:2933990090
WGK Germany:3
Risk Statements:R22
Hazard Codes:Xn:Harmful
CAS No.:123-32-0
Synonyms:View More2,5-Dimethylpiazine; KETINE; GLYCOLINE; FEMA 3272; 5-diMethyl pyrazine; 2,5-Dimethylprazin; 2,5-dimethyl-pyrazin; 2,5-Dimethyl; FEMA NUMBER 3272; 2,4-DIMETHOXYTOLUENE;
Formula:C6H8N2
Exact Mass:108.06900
Molecular Weight:108.14100
PSA:25.78000
LogP:1.09340
Properties
|
Melting Point: |
15oC |
Boiling Point: |
155oC |
Density: |
0.99 |
Storage Temp: |
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. |
Flash Point: |
63oC |
Stability: |
Stable under normal temperatures and pressures. |
Appearance: |
clear colorless to pale yellow liquid |
Vapor Pressure: |
3.98mmHg at 25C |
Refractive Index: |
1.491-1.493 |
Clear solution: |
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Freezing Point: |
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Ignition Point: |
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Vapor Density: |
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Water Solubility: |
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soluble: |
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Safety Info
|
RTECS: |
UQ2800000 |
Safety Statements: |
26-36 |
HS Code: |
2933990090 |
WGK Germany: |
3 |
Risk Statements: |
R22 |
Hazard Codes: |
Xn:Harmful |
Hazard Class: |
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Packing Group: |
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RIDADR: |
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