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2-Isopropenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(Isopropenylboronic acid pinacol ester) 126726-62-3 C9H17BO2
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Isopropenylboronic acid pinacol ester Basic information |
Product Name: | Isopropenylboronic acid pinacol ester |
Synonyms: | 2-Isopropenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Isopropenylboronic acid pinacol ester;2-(1-Methylethenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;2-Isopropenyl boronic acid pinacol ester;4,4,5,5-tetramethyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-(1-methylethenyl)-1,3,2-dioxaborolane;4,4,5,5-Tetramethyl-2-(isopropenyl)-1,3,2-dioxaborolane;2-Isopropenyl-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane(Isopropenylboronic acid pinacol ester) |
CAS: | 126726-62-3 |
MF: | C9H17BO2 |
MW: | 168.04 |
EINECS: | |
Product Categories: | Alkyl;Organoborons;Alkenyl Boronate Esters;Boronate Esters;Boronic Acids and Derivatives;Chemical Synthesis;Organometallic Reagents |
Mol File: | 126726-62-3.mol |
Isopropenylboronic acid pinacol ester Chemical Properties |
mp | 157-161 °C |
bp | 47-49 °C (9 mbar) |
density | 0.894 |
refractive index | 1.4320 |
Fp | 42 °C |
storage temp. | 2-8°C |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 10-36/37/38-43 |
Safety Statements | 16-26-36/37 |
RIDADR | UN 1993 |
HazardClass | IRRITANT |
Isopropenylboronic acid pinacol ester Usage And Synthesis |
Usage | Reagent used for• ;Palladium-catalyzed Suzuki-Miyaura cross-coupling processes1 • ;Inverse-electron-demand Diels-Alder reaction2• ;Simmons-Smith Cyclopropanation Reaction3 • ;Polyene cyclization4 • ;Stereoselective aldol reactions5 • ;Grubbs cross-metathesis reaction5 • ;Intramolecular Suzuki-Miyaura reaction5 • ;Stereoselective cross-metathesis6 • ;Dipolar cycloaddition7• ;Iodosulfonylation8 • ;Asymmetric conjugate addition and intramolecular hydroacylation9 Reagent used in preparation of various therapeutic kinase and enzymati |
Usage | suzuki reaction |
Isopropenylboronic acid pinacol ester Preparation Products And Raw materials |
Raw materials | Trimethyl borate-->Pinacol-->ISOPROPENYLMAGNESIUM BROMIDE |
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