Tetramethylsilane Tetramethylsilane 75-76-3
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Tetramethylsilane Basic information
Product Name: | Tetramethylsilane |
Synonyms: | (CH3)4Si;CT2050;Si(CH3)4;tetramethyl-silan;Tetramethylsilicane;TETRAMETHYLSILANE;TMS;SILICON TETRAMETHYL |
CAS: | 75-76-3 |
MF: | C4H12Si |
MW: | 88.22 |
EINECS: | 200-899-1 |
Product Categories: | Organics;Analytical Chemistry;NMR Spectrometry;Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Standards for NMR;Alkyl Silanes;Organometallic Reagents;Organosilicon;OthersVapor Deposition Precursors;Precursors by Metal;NMR Reference StandardsAlphabetic;NMRStable Isotopes;NMROrganometallic Reagents;Analytical Standards;OthersAlphabetic;Spectroscopy;TA - TE;organosilane;TA - TE;Alphabetic;Analytical Standards;Analytical/Chromatography;Chemical Synthesis;NMR;Organometallic Reagents;Others;T |
Mol File: | 75-76-3.mol |
Tetramethylsilane Chemical Properties |
mp | -27 °C |
bp | 26-28 °C(lit.) |
density | 0.648 g/mL at 25 °C(lit.) |
vapor pressure | 11.66 psi ( 20 °C) |
refractive index | n20/D 1.358(lit.) |
Fp | −17 °F |
storage temp. | 0-6°C |
Water Solubility | 0.02 G/L (25 ºC) |
Merck | 9229 |
BRN | 1696908 |
Stability: | Stable. Highly flammable - readily forms explosive mixtures with air. Note the boiling point close to room temperature, the low flash point and high vapour pressure. Incompatible with oxidizing agents. Refrigerate before opening. |
CAS DataBase Reference | 75-76-3(CAS DataBase Reference) |
NIST Chemistry Reference | Silane, tetramethyl-(75-76-3) |
EPA Substance Registry System | Silane, tetramethyl-(75-76-3) |
Safety Information |
Hazard Codes | Xn,F+ |
Risk Statements | 12-48/20/22-40-38-22 |
Safety Statements | 36-45-33-3/7-16-9-36/37 |
RIDADR | UN 2810 6.1/PG 3 |
WGK Germany | 3 |
F | 10 |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | I |
Tetramethylsilane Usage And Synthesis
Chemical Properties | Colorless clear liquid |
General Description | A colorless, mildly acidic volatile liquid. Flash point 0°F. Boiling point 78°F. A serious fire hazard. Mildly toxic by ingestion. Emits acrid smoke and fumes when heated to high temperatures. Less dense than water and insoluble in water, but soluble in most organic solvents. Used as an aviation fuel and as an internal standard for nmr analytical instruments. |
Air & Water Reactions | Highly flammable. Tetramethylsilane is insoluble in water. |
Reactivity Profile | Hydrides, such as Tetramethylsilane, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols. Hydrides are incompatible with acids, alcohols, amines, and aldehydes. |
Health Hazard | May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. |
Fire Hazard | HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. |
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