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31570-04-4 Antioxidant 168 31570-04-4 Antioxidant 168 31570-04-4 Antioxidant 168
Product Name: Antioxidant 168
Synonyms: Antioxidant 168 (irgafos 168);Phenol,2,4-bis(1,1-dimethylethyl,phosphite(3:1);tri(2,4-Ditertrabutylphenyl)phosphiteester;Tris(2,4-di-tert-butylphenyl)phoshit;Doverphos-S-480;Phosphorous acid tri(2,4-di-tert-butylphenyl) ester;Phosphorous acid tris[2,4-bis(tert-butyl)phenyl] ester;Tris(2,4-di-tert-butylphenyloxy)phosphine
CAS: 31570-04-4
MF: C42H63O3P
MW: 646.92
EINECS: 250-709-6
Product Categories: organophosphorus compound;Polymer Additives;Polymer Science;Achiral Phosphine;Aryl Phosphine;Additives for Plastic;Organics;Polymer Additives;Polymer Science;Stabilizers
Mol File: 31570-04-4.mol
Antioxidant 168 Chemical Properties
Melting point 181-184 °C(lit.)
Boiling point 594.2±50.0 °C(Predicted)
density -0.98
Fp 46°C (115°F)
form Powder
color white
Specific Gravity 0.98
Sensitive moisture sensitive
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
InChIKey JKIJEFPNVSHHEI-UHFFFAOYSA-N
CAS DataBase Reference 31570-04-4(CAS DataBase Reference)
EPA Substance Registry System Tris(2,4-di-tert-butylphenyl) phosphite (31570-04-4)
Safety Information
WGK Germany -
TSCA Yes
HS Code 2920900002
Antioxidant 168 Usage And Synthesis
Characterization Antioxidant 168 is a hydrolytically stable phosphite processing stabilizer. As a secondary antioxidant,Antioxidant 168 reacts during processing with hydroperoxides formed by autoxidation of polymers preventing process induced degradation and extending the performance of primary antioxidants.
Reactions
Precursor to a palladacyclic catalyst for Suzuki, Stille and Heck processes.
Ligand for Pd-catalyzed [3+2] intramolecular cycloaddition of alk-5-enylidenecyclopropanes.
Ligand for Pt-catalyzed intramolecular silaboration of alkenes.
Ligand for Ni-catalyzed aminocarbonylation of aryl halides.
Ligand for the Au-catalyzed [4+2] intramolecular cycloaddition of allene-dienes.
Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent.
Product Name: Antioxidant 168
Synonyms: Antioxidant 168 (irgafos 168);Phenol,2,4-bis(1,1-dimethylethyl,phosphite(3:1);tri(2,4-Ditertrabutylphenyl)phosphiteester;Tris(2,4-di-tert-butylphenyl)phoshit;Doverphos-S-480;Phosphorous acid tri(2,4-di-tert-butylphenyl) ester;Phosphorous acid tris[2,4-bis(tert-butyl)phenyl] ester;Tris(2,4-di-tert-butylphenyloxy)phosphine
CAS: 31570-04-4
MF: C42H63O3P
MW: 646.92
EINECS: 250-709-6
Product Categories: organophosphorus compound;Polymer Additives;Polymer Science;Achiral Phosphine;Aryl Phosphine;Additives for Plastic;Organics;Polymer Additives;Polymer Science;Stabilizers
Mol File: 31570-04-4.mol
Antioxidant 168 Chemical Properties
Melting point 181-184 °C(lit.)
Boiling point 594.2±50.0 °C(Predicted)
density -0.98
Fp 46°C (115°F)
form Powder
color white
Specific Gravity 0.98
Sensitive moisture sensitive
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
InChIKey JKIJEFPNVSHHEI-UHFFFAOYSA-N
CAS DataBase Reference 31570-04-4(CAS DataBase Reference)
EPA Substance Registry System Tris(2,4-di-tert-butylphenyl) phosphite (31570-04-4)
Safety Information
WGK Germany -
TSCA Yes
HS Code 2920900002
Antioxidant 168 Usage And Synthesis
Characterization Antioxidant 168 is a hydrolytically stable phosphite processing stabilizer. As a secondary antioxidant,Antioxidant 168 reacts during processing with hydroperoxides formed by autoxidation of polymers preventing process induced degradation and extending the performance of primary antioxidants.
Reactions
Precursor to a palladacyclic catalyst for Suzuki, Stille and Heck processes.
Ligand for Pd-catalyzed [3+2] intramolecular cycloaddition of alk-5-enylidenecyclopropanes.
Ligand for Pt-catalyzed intramolecular silaboration of alkenes.
Ligand for Ni-catalyzed aminocarbonylation of aryl halides.
Ligand for the Au-catalyzed [4+2] intramolecular cycloaddition of allene-dienes.
Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent.
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