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69739-34-0 Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester 69739-34-0 Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester 69739-34-0 Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester
Product Name: Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester
Synonyms: T-BUTYLDIMETHYLSILYLTRIFLUOROMETHANE-SULPHONATE;TBDMS TRIFLATE;TBMDS-OTF;TBS-OTF;TERT-BUTYLDIMETHYLSILYL TRIFLATE;TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE;TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULPHONATE;TRIFLUOROMETHANESULFONIC ACID TERT-BUTYLDIMETHYLSILYL ESTER
CAS: 69739-34-0
MF: C7H15F3O3SSi
MW: 264.34
EINECS: 274-102-0
Product Categories: Biochemistry;Protection & Derivatization Reagents (for Synthesis);Reagents for Oligosaccharide Synthesis;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Silyl Esters;Si-O Compounds;Synthetic Organic Chemistry;metal triflate compounds
Mol File: 69739-34-0.mol
Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Chemical Properties
Melting point <0°C
Boiling point 65-67 °C12 mm Hg(lit.)
density 1.151 g/mL at 25 °C(lit.)
refractive index n20/D 1.385(lit.)
Fp 98 °F
storage temp. 2-8°C
solubility Slightly miscible with chloroform.
form Fuming Liquid
Specific Gravity 1.151
color Clear colorless to yellow
Water Solubility DECOMPOSES
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
BRN 2370068
InChIKey WLLIXJBWWFGEHT-UHFFFAOYSA-N
CAS DataBase Reference 69739-34-0(CAS DataBase Reference)
NIST Chemistry Reference Tert-butyldimethylsilyl trifluoromethanesulfonate(69739-34-0)
Safety Information
Hazard Codes C,F
Risk Statements 10-34-37
Safety Statements 26-36/37/39-45-25-16
RIDADR UN 2920 8/PG 2
WGK Germany 3
F 10-21
Hazard Note Flammable/Corrosive
TSCA No
HazardClass 3
PackingGroup III
HS Code 29310095
Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Usage And Synthesis
Chemical Properties clear colorless to yellow fuming liquid
Uses TrifluoroMethanesulfonic acid tert-butyldiMethylsilyl ester is a highly reactive silylating agent and lewis acid capable of converting primary, secondary and tertiary alcohols to their respectctive TBDMS. TrifluoroMethanesulfonic acid tert-butyldiMethylsilyl ester is also used to covert ketones and lactones into their enol silyl ethers.
Product Name: Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester
Synonyms: T-BUTYLDIMETHYLSILYLTRIFLUOROMETHANE-SULPHONATE;TBDMS TRIFLATE;TBMDS-OTF;TBS-OTF;TERT-BUTYLDIMETHYLSILYL TRIFLATE;TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULFONATE;TERT-BUTYLDIMETHYLSILYL TRIFLUOROMETHANESULPHONATE;TRIFLUOROMETHANESULFONIC ACID TERT-BUTYLDIMETHYLSILYL ESTER
CAS: 69739-34-0
MF: C7H15F3O3SSi
MW: 264.34
EINECS: 274-102-0
Product Categories: Biochemistry;Protection & Derivatization Reagents (for Synthesis);Reagents for Oligosaccharide Synthesis;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Silyl Esters;Si-O Compounds;Synthetic Organic Chemistry;metal triflate compounds
Mol File: 69739-34-0.mol
Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Chemical Properties
Melting point <0°C
Boiling point 65-67 °C12 mm Hg(lit.)
density 1.151 g/mL at 25 °C(lit.)
refractive index n20/D 1.385(lit.)
Fp 98 °F
storage temp. 2-8°C
solubility Slightly miscible with chloroform.
form Fuming Liquid
Specific Gravity 1.151
color Clear colorless to yellow
Water Solubility DECOMPOSES
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
BRN 2370068
InChIKey WLLIXJBWWFGEHT-UHFFFAOYSA-N
CAS DataBase Reference 69739-34-0(CAS DataBase Reference)
NIST Chemistry Reference Tert-butyldimethylsilyl trifluoromethanesulfonate(69739-34-0)
Safety Information
Hazard Codes C,F
Risk Statements 10-34-37
Safety Statements 26-36/37/39-45-25-16
RIDADR UN 2920 8/PG 2
WGK Germany 3
F 10-21
Hazard Note Flammable/Corrosive
TSCA No
HazardClass 3
PackingGroup III
HS Code 29310095
Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester Usage And Synthesis
Chemical Properties clear colorless to yellow fuming liquid
Uses TrifluoroMethanesulfonic acid tert-butyldiMethylsilyl ester is a highly reactive silylating agent and lewis acid capable of converting primary, secondary and tertiary alcohols to their respectctive TBDMS. TrifluoroMethanesulfonic acid tert-butyldiMethylsilyl ester is also used to covert ketones and lactones into their enol silyl ethers.
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