Phosphorus pentachl...

Phosphorus pentachloride

Phosphorus pentachloride

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1 Kilogram

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  • Min.Order :1 Kilogram
  • Purity: 99%
  • Payment Terms : L/C,T/T,,MoneyGram,Other

Keywords

Phosphorus pentachloride 10026-13-8 PETACHLOROPHOSPHORANE

Quick Details

  • Appearance:Yellowish crystalline powder and scales
  • Application:Yellowish crystalline powder and scales
  • PackAge:in bags or customized
  • ProductionCapacity:10|Metric Ton|Day
  • Storage:
  • Transportation:by sea

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Details:

Phosphorus pentachloride Chemical Properties
mp  179-181°C (subl.)
bp  160 °C
density  1.6
storage temp.  2-8°C
form  macroporous
Water Solubility  decomposes
Sensitive  Moisture Sensitive
Merck  14,7351
CAS DataBase Reference 10026-13-8(CAS DataBase Reference)
NIST Chemistry Reference Phosphorus pentachloride(10026-13-8)
EPA Substance Registry System Phosphorane, pentachloro-(10026-13-8)
 
Safety Information
Hazard Codes  T+
Risk Statements  14-22-26-34-48/20
Safety Statements  26-36/37/39-45-7/8
RIDADR  UN 1806 8/PG 2
WGK Germany  3
RTECS  TB6125000
3-10
HazardClass  8
PackingGroup  II
Hazardous Substances Data 10026-13-8(Hazardous Substances Data)
MSDS Information
Provider Language
SigmaAldrich English
ALFA English
 
Phosphorus pentachloride Usage And Synthesis
Chemical Properties Yellowish crystalline powder and scales
General Description Phosphorus pentachloride is a greenish-yellow crystalline solid with an irritating odor. Phosphorus pentachloride is decomposed by water to form hydrochloric and phosphoric acid and heat. This heat may be sufficient to ignite surrounding combustible material. Phosphorus pentachloride is corrosive to metals and tissue. Long term exposure to low concentrations or short term exposure to high concentrations can result in adverse health effects from inhalation.
Reactivity Profile Phosphorus pentachloride is a lightly yellow, fuming crystalline material, highly caustic, corrosive and toxic. Flammable by chemical reaction. Violent exothermic reaction with water or steam. When heated to decomposition Phosphorus pentachloride emits highly toxic fumes of chlorides and oxides of phosphorus. Explosive reaction with alkaline metals (sodium, potassium), urea. Ignites on contact with fluorine. Violent reaction with aluminum, chlorine trioxide, hydroxylamine, magnesium oxide, nitrobenzene, phosphorus(III) oxide, potassium. Carbamates form explosive products [Bretherick, 5th ed., 1995, p. 1360]. Reaction with the mixture of chlorine and chlorine dioxide causes explosion [Mellor, 1941, vol. 2, p. 281; 1940, vol. 8, p. 1013].
Health Hazard Phosphorus pentachloride can cause death due to pulmonary edemaor by circulatory shock.
Fire Hazard When heated to decomposition, Phosphorus pentachloride emits highly toxic fumes of chlorides and chlorine. Will react with water or steam to produce heat and toxic and corrosive fumes. Reacts violently with moisture, chlorine trioxide, fluorine hydroxylamine, magnesium oxides, diphosphorus trioxide, sodium and potassium. Decomposed by water to form hydrogen chloride, phosphoric acids, corrosive materials, and heat. This heat may be sufficient to ignite surrounding combustible materials. Incompatible with water, magnesium oxide, chemically active metals: sodium, potassium; alkalis; aluminum; chlorine dioxide; chlorine; diphosphorus trioxide; fluorine; hydroxylamine; magnesium oxide; 3'-methyl-2-nitrobenzanilide; nitrobenzene; sodium; urea; water.

 

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