2,2'-Dichlorodiethy...

2,2'-Dichlorodiethyl ether

2,2'-Dichlorodiethyl ether

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1 Kilogram

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  • Min.Order :1 Kilogram
  • Purity: 99%
  • Payment Terms : L/C,T/T,,MoneyGram

Keywords

2,2'-Dichlorodiethyl ether 111-44-4 2,2’-dichloorethylether

Quick Details

  • Appearance:colourless liquid
  • Application:A clear colorless liquid with a sweet pleasant or nauseating odor. Flash point 131°F. Denser than water and insoluble in water. Toxic by inhalation and skin absorption. Used in cleaning compounds, pa
  • PackAge:in drums
  • ProductionCapacity:10|Metric Ton|Day
  • Storage:
  • Transportation:by sea or by air

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Details:

2,2'-Dichlorodiethyl ether Chemical Properties
mp  −47 °C(lit.)
bp  65-67 °C15 mm Hg(lit.)
density  1.22 g/mL at 25 °C(lit.)
vapor pressure  0.4 mm Hg ( 20 °C)
refractive index  n20/D 1.456(lit.)
Fp  131 °F
storage temp.  2-8°C
Water Solubility  Slightly soluble. 1.72 g/100 mL
Merck  14,3066
BRN  605317
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference 111-44-4(CAS DataBase Reference)
NIST Chemistry Reference Beta,beta'-dichloroethyl ether(111-44-4)
EPA Substance Registry System Ethane, 1,1'-oxybis[2-chloro- (111-44-4)
 
Safety Information
Hazard Codes  T+,T,F
Risk Statements  10-26/27/28-40-39/23/24/25-23/24/25-11
Safety Statements  27-28-36/37-45-7/9-28A-16
RIDADR  UN 1916 6.1/PG 2
WGK Germany  2
RTECS  KN0875000
HazardClass  6.1
PackingGroup  II
HS Code  29091900
Hazardous Substances Data 111-44-4(Hazardous Substances Data)
MSDS Information
Provider Language
2,2'-Dichlorodiethyl ether English
SigmaAldrich English
ACROS English
ALFA English
 
2,2'-Dichlorodiethyl ether Usage And Synthesis
Chemical Properties colourless liquid
General Description A clear colorless liquid with a sweet pleasant or nauseating odor. Flash point 131°F. Denser than water and insoluble in water. Toxic by inhalation and skin absorption. Used in cleaning compounds, paints, textile finishing, and as a general solvent.
Air & Water Reactions Flammable. Insoluble in water. Reacts slowly with water to form HCl. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154].
Reactivity Profile 2,2'-Dichlorodiethyl ether may form phosgene or hydrogen when heated to high temperature. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154]. Mixing in equal molar portions with the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid and oleum [NFPA 1991].
Health Hazard 2,2'-Dichlorodiethyl ether is very toxic; the probable oral lethal dose is 50-500 mg/kg, or between 1 teaspoonful and 1 ounce for a 150 pound person. It can be a central nervous system depressant in high concentrations. It is extremely irritating to the eyes, nose, and respiratory passages. It can penetrate the skin to cause serious and even fatal poisoning. Poisonous; may be fatal if inhaled, swallowed or absorbed through skin.
Fire Hazard May form phosgene or hydrogen chloride in fires. There is danger of explosion when ethers are heated or exposed to flames or sparks. Ethers tend to form peroxides; when ethers containing peroxides are heated, they can detonate. May be ignited by heat, sparks, or flames. Container may explode in heat of fire. Vapor explosion and poison hazard indoors, outdoors or in sewers. Decomposes in the presence of moisture to form hydrochloric acid. Emits toxic fumes when heated to decomposition. Reacts vigorously with oleum and chlorosulfonic acid. Ethers tend to form peroxides upon standing. Heating peroxide-containing ethers can cause detonation.

 

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