Tri-n-butylphosphine

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100 Kilogram	Negotiable

100 Kilogram

Negotiable

Min.Order :100 Kilogram
Purity: 99%
Payment Terms : L/C,D/A,D/P,T/T,Other

Keywords

RARECHEM AH PB 0251 998-40-3 C12H27P

Quick Details

Appearance:powder
Application:998-40-3
PackAge:Depended
ProductionCapacity:300|Kilogram|Month
Storage:Refrigerator
Transportation:by air or by sea

Superiority:

Tributylphosphane Basic information

Product Name:	Tributylphosphane
Synonyms:	PHOSPHORUS TRI-N-BUTYL;PHOSPHINE, TRIBUTYL;TBUP;tris(butyl)phosphine;TRI-N-BUTYLPHOSPHINE;tributylphosphane;TRIBUTYLPHOSPHINE;(n-C4H9)3P
CAS:	998-40-3
MF:	C12H27P
MW:	202.32
EINECS:	213-651-2
Product Categories:	Tertiary Phosphines;Ligand;Mitsunobu Reaction;Phosphine Ligands;Phosphines (Mitsunobu Reaction);Synthetic Organic Chemistry;organophosphorus ligand;organophosphine ligand;Catalysis and Inorganic Chemistry;Chemical Synthesis;Phosphine Compounds
Mol File:	998-40-3.mol

Tributylphosphane Chemical Properties

mp	-65 °C
bp	150 °C50 mm Hg(lit.)
density	0.81 g/mL at 25 °C(lit.)
vapor density	9 (vs air)
refractive index	n20/D 1.462(lit.)
Fp	99 °F
storage temp.	2-8°C
form	liquid
Water Solubility	insoluble
Sensitive	Moisture Sensitive/Air Sensitive
BRN	1738261
Stability:	Stable, but pyrophoric - spontaneously inflammable in air. Incompatible with oxidizing agents. Moisture sensitive.
CAS DataBase Reference	998-40-3(CAS DataBase Reference)
NIST Chemistry Reference	Phosphine, tributyl-(998-40-3)
EPA Substance Registry System	Phosphine, tributyl-(998-40-3)

Safety Information

Hazard Codes	Xi,F,C,T
Risk Statements	36/38-34-21/22-17-11-37-36/37/38-61
Safety Statements	41-36/37/39-26-16-45-43-17-5-53
RIDADR	UN 3254 4.2/PG 1
WGK Germany	3
RTECS	SZ3270000
F	10-13-23
HazardClass	4.2
PackingGroup	I

MSDS Information

Provider	Language
TBUP	English
ACROS	English
SigmaAldrich	English
ALFA	English

Tributylphosphane Usage And Synthesis

Chemical Properties	Clear liquid
Usage	1,4-addition catalyst; used with disulfides for the thioetherification of alcohols; acylation catalyst; used to prepare active esters.
Usage	suzuki reaction
General Description	Tributylphosphane is a colorless to yellowish liquid with a strong garlic-like odor. Tributylphosphane is insoluble in water. Tributylphosphane is liable to heat and ignite spontaneously in air. If involved in a fire phosphine gas, a highly flammable and toxic gas, will evolve. Tributylphosphane is irritating to mucous membranes.
Air & Water Reactions	Highly flammable. May ignite on contact with air or moist air. Insoluble in water.
Reactivity Profile	Organophosphates, such as Tributylphosphane, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Health Hazard	Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire Hazard	Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.

Tributylphosphane Preparation Products And Raw materials

Preparation Products	ORNOPROSTIL-->CYANOMETHYLENETRIBUTYLPHOSPHORANE-->TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE-->Cetyltributylphosphonium bromide
Raw materials	Diethyl ether-->Magnesium-->Phosphorus trichloride-->1-Bromobutane

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