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RARECHEM AH PB 0251 14694-95-2 C54H45ClP3Rh
Chlorotris(triphenylphosphine)rhodium(I) Basic information |
Product Name: | Chlorotris(triphenylphosphine)rhodium(I) |
Synonyms: | DECARBON;CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I);CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODATE (I);TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE POLYMER BOUND;WILKINSON CATALYST |
CAS: | 14694-95-2 |
MF: | C54H45ClP3Rh |
MW: | 925.21 |
EINECS: | 238-744-5 |
Product Categories: | Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;metal-phosphine complexes;chemical reaction,pharm,electronic,materials |
Mol File: | 14694-95-2.mol |
Chlorotris(triphenylphosphine)rhodium(I) Chemical Properties |
mp | 245-250 °C (dec.) |
bp | >170°C |
storage temp. | 2-8°C |
Water Solubility | insoluble |
Merck | 14,10047 |
CAS DataBase Reference | 14694-95-2(CAS DataBase Reference) |
NIST Chemistry Reference | chlorotris(triphenylphosphine)rhodium(14694-95-2) |
EPA Substance Registry System | Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-(14694-95-2) |
Safety Information |
Hazard Codes | C,Xi |
Risk Statements | 34-36/38 |
Safety Statements | 22-24/25-37/39-28A-26-15 |
WGK Germany | 1 |
F | 8-10-23 |
TSCA | Yes |
HS Code | 28439090 |
MSDS Information |
Provider | Language |
---|---|
Chlorotris(triphenylphosphine)rhodium(I) | English |
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Chlorotris(triphenylphosphine)rhodium(I) Usage And Synthesis |
Chemical Properties | magenta crystals |
Usage | suzuki reaction |
Usage | Tris(triphenylphosphine)rhodium Chloride is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodium(I) Chloride is also used i n the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds. |
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