RARECHEM AH PB 0251 24850-33-7 C15H32Sn
Allyltributyltin Basic information |
Product Name: | Allyltributyltin |
Synonyms: | ALLYLTRIBUTYLSTANNANE;ALLYLTRIBUTYLTIN;ALLYLTRIBUTYLTIN(IV);ALLYLTRI-N-BUTYLTIN;TRIBUTYL-2-PROPENYLSTANNANE;Stannane, tributyl-2-propenyl-;Allytri-N-Butyltin;Allyltri-n-butyltin,97% |
CAS: | 24850-33-7 |
MF: | C15H32Sn |
MW: | 331.12 |
EINECS: | 246-494-3 |
Product Categories: | Alkyl Metals;Sn (Tin) Compounds;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Synthetic Organic Chemistry;Typical Metal Compounds;Organometallic Reagents;Organotin;Organotins;Stannanes;Chemical Synthesis;Organometallic Reagents |
Mol File: | 24850-33-7.mol |
Allyltributyltin Chemical Properties |
bp | 88-92 °C0.2 mm Hg(lit.) |
density | 1.068 g/mL at 25 °C(lit.) |
refractive index |
n |
Fp | >230 °F |
storage temp. | 2-8°C |
Sensitive | Air Sensitive |
BRN | 3588340 |
CAS DataBase Reference | 24850-33-7(CAS DataBase Reference) |
NIST Chemistry Reference | Allyltributyltin(24850-33-7) |
Safety Information |
Hazard Codes | T,N |
Risk Statements | 21-25-36/38-48/23/25-50/53-23/24/25 |
Safety Statements | 35-36/37/39-45-60-61-28-27-26 |
RIDADR | UN 2788 6.1/PG 2 |
WGK Germany | 3 |
F | 13 |
TSCA | No |
HazardClass | 6.1 |
PackingGroup | II |
MSDS Information |
Provider | Language |
---|---|
Tributyl-2-propenylstannane | English |
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Allyltributyltin Usage And Synthesis |
Chemical Properties | CLEAR COLOURLESS LIQUID |
Usage | Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7 |
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