TIANFU-CHEM - Sulfur tetrafluoride

Min.Order / FOB Price:Get Latest Price

1 Kilogram	Negotiable

1 Kilogram

Negotiable

Min.Order :1 Kilogram
Purity: 99.0%
Payment Terms : L/C,D/A,D/P,T/T,,MoneyGram,Other

Keywords

Sulfur tetrafluoride 7783-60-0 F4S

Quick Details

Appearance:Solid
Application:Organic synthesis
PackAge:IN 25kg drums
ProductionCapacity:10|Metric Ton|Month
Storage:In Room Temperature
Transportation:As per the MSDS

Superiority:

Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble metal catalysts, synthesis of electronic chemical materials and general chemicals Imp&Exp trading business. The company is located in Zhengzhou High-tech Development Zone with import and export license. We passed ISO 9001:2008 in 2009, and won "High-tech Enterprise" by provincial government in 2013. Our STPP and SHMP has reached an annual output of 30000 tons and has successfully passed SGS, CIQ audits on many occasions.

In 2011 we entered the fine chemical market of Noble Metal Catalyst ,Organic Phosphine Ligands and OLED intermediates.With the joint efforts of our senior experts and professional technicians, Tianfu has developed more than 500 compounds, which are widely used in the fields of production and life science. The objective of the company is to put quality first and put our customer’s needs first - the satisfaction of our customers is the company's ultimate goal. Improving product quality and service level is our responsibility, and creating more value for our customer’s is our purpose. We are constantly striving to make Henan Tianfu a leading chemical supplier, and hope to create a better future with you.

Details:

Sulfur tetrafluoride Basic information

Selective organic fluorinating agent Category Toxicity Acute toxicity Flammability hazard characteristics Storage characteristics Extinguishing agent Professional standards

Product Name:	Sulfur tetrafluoride
Synonyms:	sulfur fluoride;SULFUR TETRAFLUORIDE;SULPHUR TETRAFLUORIDE;(beta-4)-sulfurfluoride(sf4;SF4;Sulfur fluoride (SF4);Sulfur fluoride (SF4), (T-4)-;Tetrafluorosulfurane
CAS:	7783-60-0
MF:	F4S
MW:	108.06
EINECS:	232-013-4
Product Categories:	Inorganics;Inorganic Fluorides;FluoridesSynthetic Reagents;Chemical Synthesis;Compressed and Liquefied GasesMicro/Nanoelectronics;C-X Bond Formation (Halogen);Electronic Chemicals;Fluorination;Synthetic Reagents
Mol File:	7783-60-0.mol

Sulfur tetrafluoride Chemical Properties

mp	−121.5-−120.5 °C(lit.)
bp	−40.4 °C(lit.)
density	1.941
vapor pressure	140 psi ( 21 °C)
Merck	13,9068
CAS DataBase Reference	7783-60-0(CAS DataBase Reference)
NIST Chemistry Reference	Sulfur tetrafluoride(7783-60-0)
EPA Substance Registry System	Sulfur fluoride (SF4), (T-4)-(7783-60-0)

Safety Information

Hazard Codes	T+,C,T
Risk Statements	14-26-34-37
Safety Statements	26-36/37/39-38-45
RIDADR	UN 2418 2.3
WGK Germany	3
RTECS	WT4800000
Hazard Note	Highly Toxic/Corrosive
HazardClass	2.3
Hazardous Substances Data	7783-60-0(Hazardous Substances Data)

MSDS Information

Provider	Language
Sulfur fluoride	English
SigmaAldrich	English

Sulfur tetrafluoride Usage And Synthesis

Selective organic fluorinating agent	Sulfur tetrafluoride is a selective organic fluorinating agent, S atoms form σ bond with sp3d hybrid orbitals on its molecular structure, molecular shape is distorted tetrahedral, at normal temperature and pressure, it is colorless gas with strong stimulus foul odor of gas which similar to sulfur dioxide, it is toxic, it does not burn and explode in the air, at 600 ℃ it remains stable. It strong hydrolyzes and emits white smoke in the air. When encounteres water environment, it will cause corrosion of similar to hydrofluoric acid. It fully hydrolyzes into hydrofluoric acid and sulfur dioxide, the partial hydrolysis can produce toxic thionyl fluoride, alkali solution can fully absorb into it and turn it into non-toxic salts; it is soluble in benzene. Sulfur tetrafluoride (abbreviation of SF4) is currently widely used and it is the most potent selective organic fluorinating agent, it can selectively fluorinate carbonyl and hydroxyl (substituted oxygen of carbonyl compounds); it is widely used in chemical high-grade and high-end liquid crystal material medicine, pesticide intermediates production industry, it has irreplaceable position. The above information is edited by the chemicalbook of Wang Xiaodong.
Category	Harmful gases.
Toxicity	Mid toxicity.
Acute toxicity	Inhalation - rat LCL0: 19 PPM / 4h.
Flammability hazard characteristics	It can decompose into toxic hydrogen fluoride and sulfur dioxide gas when meets water.
Storage characteristics	Treasury ventilation low-temperature drying; it should be stored separately with acids, flammable, explosive materials.
Extinguishing agent	water
Professional standards	TWA 2.5 mg (fluorine) / cubic meter
General Description	Sulfur tetrafluoride is a colorless gas with a distinct sulfur odor. Sulfur tetrafluoride is highly toxic by inhalation and a strong irritant to skin, eyes and mucous membranes. Sulfur tetrafluoride reacts vigorously with water and acids to yield toxic fluoride and sulfur oxide fumes and an acidic solution. Sulfur tetrafluoride is heavier than air. Under prolonged exposure to fire or intense heat the containers may violently rupture or rocket. Sulfur tetrafluoride is used as a fluoridizing agent and as an oil repellent.
Air & Water Reactions	Violent reaction with water. Sulfur tetrafluoride reacts vigorously with water and acids to yield toxic fluoride and sulfur oxide fumes and an acidic solution.
Reactivity Profile	Sulfur tetrafluoride is a highly toxic and corrosive gas. On contact with water, steam, or mineral acids Sulfur tetrafluoride decomposes and produces toxic and highly irritating fumes. When heated to decomposition Sulfur tetrafluoride emits very toxic fluoride and sulfur oxides fumes [Lewis, 3rd ed., 1993, p. 1197]. Explosively violent reactions with 2-(hydroxymethyl)furan or 2-methyl-3-butyn-2-ol even below -50° C have been recorded [Bretherick, 5th ed., 1995, p. 1432]. Ignition or explosion may occur on contact with dioxygen difluoride even below -100° C [Streng, A. G., Chem. Rev., 1963, 63, p. 615].
Health Hazard	Sulfur tetrafluoride is highly toxic by inhalation; it is a strong irritant to eyes and mucous membranes. Poisonous; may be fatal if inhaled. Contact may cause burns to skin and eyes. Contact with liquid may cause frostbite.
Fire Hazard	Container may explode in heat of fire. When heated to decomposition, Sulfur tetrafluoride emits very toxic fumes of fluorides and sulfur oxides. Reacts violently with water. Sulfur tetrafluoride is decomposed by concentrated sulfuric acid. Thermostable to 1112F.

Sulfur tetrafluoride Preparation Products And Raw materials

Preparation Products

Diethylaminosulfur trifluoride-->5-(trifluoromethyl)thiazol-2-amine

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