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Thiophosgene Basic information |
Product Name: | Thiophosgene |
Synonyms: | Carbon chlorosulfide;carbonchlorosulfide;Carbonic dichloride, thio-;carbonothioicdichloride;Carbonyl chloride, thio-;CSCl2;Dichlorothiocarbonyl;Phosgene, thio- |
CAS: | 463-71-8 |
MF: | CCl2S |
MW: | 114.98 |
EINECS: | 207-341-6 |
Product Categories: | Organics |
Mol File: | 463-71-8.mol |
Thiophosgene Chemical Properties |
bp | 73 °C |
density | 1.508 |
vapor density | 4 (vs air) |
refractive index |
n |
Fp | 62 °C |
storage temp. | 2-8°C |
Water Solubility | slow decomposition in cold, fast in hot water |
Stability: | Stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8 C. |
CAS DataBase Reference | 463-71-8(CAS DataBase Reference) |
NIST Chemistry Reference | Carbonothioic dichloride(463-71-8) |
EPA Substance Registry System | Carbonothioic dichloride(463-71-8) |
Safety Information |
Hazard Codes | T |
Risk Statements | 22-23-36/37/38 |
Safety Statements | 7-9-36/37-45-7/9 |
RIDADR | UN 2474 6.1/PG 2 |
WGK Germany | 1 |
RTECS | XN2450000 |
F | 19-21 |
HazardClass | 6.1(a) |
PackingGroup | II |
Hazardous Substances Data | 463-71-8(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
Thiophosgene | English |
ACROS | English |
SigmaAldrich | English |
Thiophosgene Usage And Synthesis |
Chemical Properties | reddish liquid |
Usage | Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000). |
General Description | A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption. |
Air & Water Reactions | Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot. |
Reactivity Profile | Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids. |
Health Hazard | Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach. |
Thiophosgene Preparation Products And Raw materials |
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