100-39-0 Benzyl bromide 1-Bromotoluene
Benzyl bromide Basic information
Product Name: Benzyl bromide
Synonyms: (bromomethyl)-benzen;1-Bromotoluene;ai3-15300;alpha-bromo-toluen;Bromophenylmethane;-Bromotoluene;Bromotoluene, alpha;bromotoluene,alpha
CAS: 100-39-0
MF: C7H7Br
MW: 171.03
EINECS: 202-847-3
Product Categories: Pharmaceutical Intermediates;Aromatic Halides (substituted);Organics;Benzyl;Biochemistry;Reagents for Oligosaccharide Synthesis;Aryl;Building Blocks;C7;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks
Mol File: 100-39-0.mol
Benzyl bromide Structure
Benzyl bromide Chemical Properties
mp -3 °C
bp 198-199 °C(lit.)
density 1.44 g/mL at 20 °C
vapor density 5.8 (vs air)
refractive index n20/D 1.575(lit.)
Fp 188 °F
storage temp. Store at RT.
Sensitive Moisture Sensitive/Light Sensitive
Merck 14,1128
BRN 385801
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference 100-39-0(CAS DataBase Reference)
NIST Chemistry Reference Benzene, (bromomethyl)-(100-39-0)
EPA Substance Registry System Benzene, (bromomethyl)-(100-39-0)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 39-2
RIDADR UN 1737 6.1/PG 2
WGK Germany 2
RTECS XS7965000
F 9-19-21
HazardClass 6.1
PackingGroup II
Hazardous Substances Data 100-39-0(Hazardous Substances Data)
Benzyl bromide Usage And Synthesis
Chemical Properties Clear light amber liquid
General Description A colorless liquid with an agreeable odor. Toxic by inhalation and by skin absorption. Benzyl bromide is slightly soluble in water and denser than water (density 1.44 g / cm3 (Aldrich)). A lachrymator. Corrosive to metals and tissue.
Air & Water Reactions Sensitive to exposure to light and moisture. Slightly soluble in water.
Reactivity Profile Benzyl bromide reacts with water, alcohols, common metals (except nickel and lead), bases, amines and oxidizing agents. . Benzyl bromide stored over activated 4A molecular sieve burst a bottle due to condensation-polymerization reaction with generation of HBr gas, [Chem. Eng. News, 1979, 57(12), 74].
Health Hazard Inhalation causes irritation of nose and throat; severe exposure may cause pulmonary edema. Vapors cause severe eye irritation; liquid can burn eyes. Skin contact causes irritation. Ingestion causes irritation of mouth and stomach.
Benzyl bromide Preparation Products And Raw materials
Preparation Products 3,5-BIS(BENZYLOXY)BENZYL BROMIDE-->Sulindac-->Benzyldodecyldimethylammonium bromide-->CYCLOPROTHRIN-->trans-2,5-Dimethylpiperazine-->N-(4-(Benzyloxy)benzylidene)-4-fluoroaniline-->O-(2-MethoxyEthoxy)BenzeneSulfonamide-->BOC-3-IODO-D-ALANINE BENZYL ESTER-->4-BENZYLOXY-3-METHOXYBENZALDEHYDE-->3,5-Dibenzyloxybenzyl alcohol-->N-BOC-O-Benzyl-L-serine-->4-(Boc-Aminomethyl)piperidine-->2-(Boc-aminomethyl)-piperidine-->1-BENZYL-1,4-DIAZEPANE-->4-Benzyloxybenzeneboronic acid-->Anagrelide-->3-METHYLADENINE-->Diethyl benzylmalonate-->Cinosulfuron-->Candesartan-->4-BENZYLOXYANILINE-->(S)-(-)-N-Benzyl-1-phenylethylamine-->TERBUTALINE SULFATE-->alpha-[4-[2-(diethylamino)ethoxy]phenyl]-alpha-phenylphenethyl alcohol -->(R)-(-)-Benzyl glycidyl ether-->1-BENZYL-2-IMIDAZOLECARBOXYLIC ACID-->3-Benzyloxybenzaldehyde-->4-Amino-1-benzylpiperidine-->Indobufen-->5-Hydroxyindole-->7-Hydroxyindole-->6-CHLORO-1H-PYRROLO[2,3-B]PYRIDINE-->2-(4-BENZYLOXYPHENYL)ETHANOL-->2-Methyl-1-phenyl-2-propanol-->4-METHYL-1-PHENYL-2-PENTANOL-->CROCONAZOLE-->Benzyldimethylhexadecylammonium chloride-->Butenafine hydrochloride-->2-Hydroxydiphenylmethane-->1,3,5-Benzenetricarboxaldehyde
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