Lithium amide 7782-89-0 H2LiN
Lithium amide Basic information |
Product Name: | Lithium amide |
Synonyms: | lithamide;LITHIUM AMIDE;Lithiumamideoffwhitepowder;LITHIUM AMIDE, HYDROGEN STORAGE GRADE;LITHIUM AMIDE, POWDER, 95%;Lithiumamide,95%;Lithium amide (Li(NH2));Lithiumamid |
CAS: | 7782-89-0 |
MF: | H2LiN |
MW: | 22.96 |
EINECS: | 231-968-4 |
Product Categories: | Inorganics;Organic Bases;Alternative Energy;AmidesChemical Synthesis;Inorganic Bases;Materials for Hydrogen Storage;Synthetic Reagents;metal amide;Alternative Energy;Amides;Chemical Synthesis;Inorganic Bases;Materials for Hydrogen Storage;Materials Science;Synthetic Reagents |
Mol File: | 7782-89-0.mol |
Lithium amide Chemical Properties |
Melting point | 373 °C |
Boiling point | 430 °C |
density | 1.178 g/mL at 25 °C(lit.) |
refractive index | 1.178g/mL |
storage temp. | water-free area |
form | powder |
Water Solubility | reacts |
Sensitive | Air & Moisture Sensitive |
Merck | 14,5522 |
CAS DataBase Reference | 7782-89-0(CAS DataBase Reference) |
EPA Substance Registry System | Lithium amide (Li(NH2))(7782-89-0) |
Safety Information |
Hazard Codes | F,C |
Risk Statements | 14/15-29-34-20/21/22-15-14-11 |
Safety Statements | 26-36/37/39-43-45-7/8-43B-16-3/7/9 |
RIDADR | UN 1390 4.3/PG 2 |
WGK Germany | 2 |
RTECS | OJ5590000 |
HazardClass | 4.3 |
PackingGroup | II |
Hazardous Substances Data | 7782-89-0(Hazardous Substances Data) |
Lithium amide Usage And Synthesis |
Chemical Properties | white to grey fine powder |
Usage | Reagent for synthesis of: Antiinflamatory and preoresolving protectin D11 Chemotype dipeptidyl peptidase IV inhibitors2 Sterically congested triarylamines3 Dyes displaying large Stokes shifts4 GM1 ganglioside derivatives5Reagent for cross-coupling of aryl chlorides and amines6 |
General Description | White crystalline powder with an odor of ammonia. Denser than water. |
Reactivity Profile | Powdered Lithium amide is highly reactive. A strong base. Reacts to release toxic ammonia gas with water. Forms explosive peroxide on storage. |
Health Hazard | Highly toxic: contact with water produces toxic gas, may be fatal if inhaled. Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution. |
Fire Hazard | Produce flammable and toxic gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Containers may explode when heated. Runoff may create fire or explosion hazard. |
Lithium amide Preparation Products And Raw materials |
Preparation Products | 5-BROMO-2-(DIMETHYLAMINO)PYRIMIDINE-->N,N-diethyl-1-propynylamine-->dioctadecyl [[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]phosphonate |
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