6-Bromoquinoline

6-Bromoquinoline
6-Bromoquinoline
6-Bromoquinoline

6-Bromoquinoline

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6-Bromoquinoline 5332-25-2 C9H6BrN

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  • Appearance:powder
  • Application:5332-25-2
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  • ProductionCapacity:300|Kilogram|Month
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6-Bromoquinoline Basic information
Bromoquinoline Application and synthetic method
Product Name: 6-Bromoquinoline
Synonyms: 6-BROMOQUINOLINE;TIMTEC-BB SBB001559;6-bromo-quinolin;Quinoline, 6-bromo-;6-BROMOQUINOLINE 95+%;6-BROMOOQUINOLINE;6-Bromoquinoline ,98%;NSC 3996
CAS: 5332-25-2
MF: C9H6BrN
MW: 208.05
EINECS: 206-363-3
Product Categories: blocks;Bromides;Quinolines;Halides;Quinolines, Isoquinolines & Quinoxalines;Quinoline&Isoquinoline;Miscellaneous;Quinoline Derivertives;Aromatics Compounds;Haloquinolines;quinoline;Aromatics;Heterocycles;Quinolines, Isoquinolines & Quinoxalines;Boronic Acid;Heterocyclic Compounds;Building Blocks;Halogenated Heterocycles;Heterocyclic Building Blocks;QuinolinesHeterocyclic Building Blocks
Mol File: 5332-25-2.mol
6-Bromoquinoline Structure
 
6-Bromoquinoline Chemical Properties
Melting point  19°C
Boiling point  116 °C / 6mmHg
density  1.55
refractive index  n20/D 1.663
Fp  19 °C
storage temp.  Refrigerator
CAS DataBase Reference 5332-25-2(CAS DataBase Reference)
NIST Chemistry Reference 6-Bromo quinoline(5332-25-2)
EPA Substance Registry System Quinoline, 6-bromo-(5332-25-2)
 
Safety Information
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-41-37/38-22-20/21/22
Safety Statements  26-37/39-39-36
Hazard Note  Irritant
HazardClass  IRRITANT
MSDS Information
 
 
6-Bromoquinoline Usage And Synthesis
Bromoquinoline There are seven positional isomers of bromoquinoline and their main properties are listed below: There are seven positional isomers of bromoquinoline and their main properties are listed
Application and synthetic method 3-bromo-quinoline is reacted with mixed acid for generating 3-bromo-5-nitro-quinoline, which heats together with potassium permanganate for being oxidation into 5-bromo-2, 3-pyridine dicarboxylic acid. 
6-bromo-quinoline is heated together with nitric acid to generate 6-bromo-8-nitro quinolone with further reaction with potassium permanganate for being oxidized to 2, 3-pyridinedicarboxylic acid. 
2-bromo-quinolien can be synthesized through the reaction between 2-hydroxy quinoline and phosphorus pentabromide.
Quinoline perbromide is heated at 180 °C for generating 3-bromo-quinoline.
From the heating between 4-hydroxy quinoline and phosphorus pentabromide, or from the diazotization reaction via 4-aminoquinoline to generate 4-bromo-quinoline;
5-bromo-quinoline is synthesize by the heating reaction between m-bromo-aniline, glycerol, m-bromo nitrobenzene and concentrated sulfuric acid, or from the diazotization reaction of 5-aminoquinoline.
6-bromo-quinoline can be synthesized from the heating of bromoaniline, glycerol, concentrated sulfuric acid, and p-bromo-nitrobenzene. 7-bromo-quinoline can be synthesized from the diazotization reaction of 7-aminoquinoline.
8-bromo-quinoline can be synthesized from the heating reaction of o-bromo-aniline, glycerol, concentrated sulfuric acid and o-bromo nitrobenzene.
application: as organic synthesis reagents.
The above information is edited by the Chemicalbook of Dai Xiongfeng.
Chemical Properties Thick Oil
 
6-Bromoquinoline Preparation Products And Raw materials
Raw materials Sodium hydroxide-->Sulfuric acid -->Tetrahydrofuran-->Toluene-->1-Butanol-->Zinc chloride-->Glycerol-->Acrolein-->4-Bromoaniline-->Chloranil-->1-Bromo-4-nitrobenzene

 

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