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75-35-4 VINYLIDENE CHLORIDE 1,1-DCE
Product Name: VINYLIDENE CHLORIDE
Synonyms: 1,1-DCE;1,1-Dichlorethen;1,1-Dichlorethylen;1,1-dichloro-ethen;1,1-dichloro-ethylen;1,1-dichloroethylene (vinylidine chloride);1,1-Dichoroethene;as-dichloroethylene
CAS: 75-35-4
MF: C2H2Cl2
MW: 96.94
EINECS: 200-864-0
Product Categories: Industrial/Fine Chemicals;Vinylchloride;Gas Cylinders;Halides (Low Boiling point);Synthetic Organic Chemistry;Standard Solutions (VOC);Analytical Chemistry;Standard Solution of Volatile Organic Compounds for Water & Soil Analysis;Alpha Sort;D;DAlphabetic;DIA - DIC;Volatiles/ Semivolatiles
Mol File: 75-35-4.mol
VINYLIDENE CHLORIDE Structure
VINYLIDENE CHLORIDE Chemical Properties
Melting point -122 °C
Boiling point 31.2 °C
density 1.213 g/mL at 20 °C(lit.)
vapor density 3.46 (vs air)
vapor pressure 9.68 psi ( 20 °C)
refractive index n20/D 1.426
Fp −9 °F
storage temp. 2-8°C
Sensitive Light Sensitive
Merck 14,9996
BRN 1733365
Stability: Stable. Very flammable - note low flash point. Vapour may travel considerable distances to a source of ignition. Incompatible with strong oxidizing agents, alcohols, halides, sopper, aluminium. Rapidly absorbs oxygen from the air and forms explosive peroxides. Light and water promote self-polymerisation. May form explosive mix
CAS DataBase Reference 75-35-4(CAS DataBase Reference)
Safety Information
Hazard Codes F+,Xn,T,F
Risk Statements 12-20-40-39/23/24/25-23/24/25-11
Safety Statements 7-16-29-36/37-46-45
RIDADR UN 1303 3/PG 1
WGK Germany 3
RTECS KV9275000
F 1-8-10
HazardClass 3
PackingGroup I
Chemical Properties colourless liquid
Definition ChEBI: A member of the class of chloroethenes that is ethene in which both of the hydrogens attached to one of the carbons are replaced by chlorines.
General Description A clear colorless liquid with a chloroform-like odor. Flash point 0°F. Boiling point 99°F. Denser (at 10.1 lb / gal) than water and insoluble in water. Hence sinks in water. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Vapors heavier than air.
Air & Water Reactions Highly flammable. Insoluble in water.
Reactivity Profile Peroxidizable monomer, such as VINYLIDENE CHLORIDE, may initiate exothermic polymerization of the bulk material [Bretherick 1979. p. 160, 187]. Mixing vinylidene chloride in equal molar portions in a closed container with any of the following substances caused the temperature and pressure to increase: chlorosulfonic acid, nitric acid, or oleum [NFPA 1991]. It's reaction products with ozone are particularly dangerous, [Dow Chemical, 1968]. This may extend to other powerful oxidants, as various peroxides are produced.
Health Hazard Vapor can cause dizziness and drunkenness; high levels cause anesthesia. Liquid irritates eyes and skin.
VINYLIDENE CHLORIDE Preparation Products And Raw materials
Raw materials Hydrochloric acid-->Chlorine-->1,1,2-Trichloroethane
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