CAS No.556-61-6 M...

CAS No.556-61-6   Methyl isothiocyanate
CAS No.556-61-6   Methyl isothiocyanate

CAS No.556-61-6 Methyl isothiocyanate

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  • Min.Order :1 Kilogram
  • Purity: 98.0%Min
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Keywords

556-61-6 Methyl isothiocyanate 98%

Quick Details

  • Appearance:Solid
  • Application:Pharma intermediates
  • PackAge:1KG -200KG Drum with pallet
  • ProductionCapacity:5000|Kilogram|Year
  • Storage:2-8°C
  • Transportation:by sea or by air or by courier

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CAS No.556-61-6

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Methyl isothiocyanate Basic information
Product Name: Methyl isothiocyanate
Synonyms: AKOS BBS-00004313;isothiocyanatomethane;ISOTHIOCYANIC ACID METHYL ESTER;METHYL MUSTARD-OIL;METHYL ISOTHIOCYANATE;MIT;MITC;MTC
CAS: 556-61-6
MF: C2H3NS
MW: 73.12
EINECS: 209-132-5
Product Categories: Organics;Organic Building Blocks;Sulfur Compounds;Thiocyanates/Isothiocyanates;Alpha sort;Fungicides;Herbicides;H-MAlphabetic;M;META - METHPesticides&Metabolites;NematicidesPesticides;Others;OthersPesticides&Metabolites;Pesticides;Pesticides&Metabolites;Isothiocyanates
Mol File: 556-61-6.mol
Methyl isothiocyanate Structure
 
Methyl isothiocyanate Chemical Properties
Melting point  30-34 °C(lit.)
Boiling point  117-118 °C(lit.)
density  1.069 g/mL at 25 °C(lit.)
vapor pressure  21 mm Hg ( 20 °C)
FEMA  4426 | METHYL ISOTHIOCYANATE
refractive index  nD37 1.5258
Fp  90 °F
storage temp.  2-8°C
solubility  H2O: slightly soluble
form  Low Melting Solid
color  White to pale yellow
Water Solubility  7.6 g/L
Sensitive  Moisture Sensitive
Merck  14,6092
BRN  605319
Stability: Stable. Incompatible with strong oxidizing agents, alcohols, strong bases, amines.
CAS DataBase Reference 556-61-6(CAS DataBase Reference)
NIST Chemistry Reference Methane, isothiocyanato-(556-61-6)
EPA Substance Registry System Methane, isothiocyanato-(556-61-6)
 
Safety Information
Hazard Codes  T,N
Risk Statements  23/25-34-43-50/53
Safety Statements  36/37-38-45-60-61
RIDADR  UN 2477 6.1/PG 1
WGK Germany  3
RTECS  PA9625000
21
TSCA  Yes
HazardClass  6.1
PackingGroup  I
Hazardous Substances Data 556-61-6(Hazardous Substances Data)
Methyl isothiocyanate Usage And Synthesis
Chemical Properties colourless solid
Uses Usually used to study the effect of pesticide Metam (methyl isothiocyanate is its active ingredient) in the streamside microbial communities of the upper Sacramento river
Definition ChEBI: An isothiocyanate having a methyl group attached to the nitrogen.
General Description A colorless liquid with a sharp odor. Lethal by inhalation of even small quantities of vapor. Does not have odor warning characteristics at low concentrations. Do not rely on the sense of smell to warn about the presence of vapors. Denser than water. Flash point below 20°F. May cause tearing and irritate the eyes, skin, nose and throat.
Air & Water Reactions Highly flammable. Methyl isothiocyanate reacts with water to form carbon dioxide and methylamine gases.
Reactivity Profile Isocyanates and thioisocyanates, such as Methyl isothiocyanate, are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerization reactions in these materials. Some isocyanates react with water to form amines and liberate carbon dioxide. Polyurethanes are formed by the condensation reaction of diisocyanates with, for example, ethyl glycol.
Health Hazard Very toxic; probable human oral lethal dose is 50-500 mg/kg, or between 1 teaspoonful and 1 oz. for a 70 kg (150 lb.) person. Highly irritating to skin, mucous membrances, and eyes. Human oral minimum lethal dose: approximately 1 g/kg.
Fire Hazard (Non-Specific -- Pesticide, Solid, n.o.s.) Methyl isothiocyanate may burn, but does not ignite readily. Fire may produce irritating or poisonous gases. When heated Methyl isothiocyanate emits very dangerous cyanides and sulfur compounds. Do not store below -4F or at elevated temperatures. Keep away from sparks.
 
Methyl isothiocyanate Preparation Products And Raw materials
Raw materials METHYLAMINE-->Carbon disulphide-->Ethyl chloroformate-->ISOTHIOCYANATE, POLYMER-BOUND, 200-400
Preparation Products N-METHYLTHIOUREA-->Methimazole

 

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