C5H7ClO3 Ethyl mal...

C5H7ClO3  Ethyl malonyl chloride  36239-09-5

C5H7ClO3 Ethyl malonyl chloride 36239-09-5

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Ethyl malonyl chloride 36239-09-5 C5H7ClO3

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  • Appearance:Powder
  • Application:36239-09-5
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  • ProductionCapacity:100|Metric Ton|Day
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Details:

Ethyl malonyl chloride Basic information
Product Name: Ethyl malonyl chloride
Synonyms: 3-chloro-3-oxo-propanoicaciethylester;Propanoic acid, 3-chloro-3-oxo-, ethyl ester;MALONIC ACID MONOETHYL ESTER CHLORIDE;AURORA KA-3051;(CHLOROFORMYL)ACETIC ACID ETHYL ESTER;ETHYL 3-CHLORO-3-OXOPROPIONATE;ETHYL 2-(CHLOROCARBONYL)ACETATE;ETHYL MALONYL CHLORIDE
CAS: 36239-09-5
MF: C5H7ClO3
MW: 150.56
EINECS: 252-934-5
Product Categories: Aliphatics;Acid Halides;Building Blocks;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Pharmaceutical raw material;Pharmaceutical intermdiate
Mol File: 36239-09-5.mol
Ethyl malonyl chloride Structure
 
Ethyl malonyl chloride Chemical Properties
Boiling point  79-80 °C25 mm Hg(lit.)
density  1.196 g/mL at 20 °C
refractive index  n20/D 1.429(lit.)
Fp  154 °F
storage temp.  2-8°C
form  Liquid
color  Clear yellow to brown
Water Solubility  REACTS
Sensitive  Moisture Sensitive
BRN  636215
CAS DataBase Reference 36239-09-5(CAS DataBase Reference)
NIST Chemistry Reference Ethyl malonyl chloride(36239-09-5)
 
Safety Information
Hazard Codes  C
Risk Statements  14-34
Safety Statements  7-26-36/37/39-45-36/39
RIDADR  UN 3265 8/PG 3
WGK Germany  3
10-21
Hazard Note  Corrosive
HazardClass  8
PackingGroup  II
MSDS Information
Provider Language
Ethyl (chloroformyl)acetate English
SigmaAldrich English
ACROS English
ALFA English
 
Ethyl malonyl chloride Usage And Synthesis
Chemical Properties clear yellow to brown liquid
Uses Employed in the synthesis of 3-pyrrolin-2-ones via amidation with propargylamines and subsequent base catalyzed 5-exo-dig cyclization.1

 

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