C12H14N4O4S2 Thioph...

C12H14N4O4S2	Thiophanate-methyl 23564-05-8

C12H14N4O4S2 Thiophanate-methyl 23564-05-8

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Thiophanate-methyl 23564-05-8 C12H14N4O4S2

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  • Appearance:Powder
  • Application:23564-05-8
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  • ProductionCapacity:100|Metric Ton|Day
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Thiophanate-methyl Basic information
Description References
Product Name: Thiophanate-methyl
Synonyms: (1,2-phenylenebis(iminocarbonothioyl))bis-carbamicacidimethylester;[1,2-phenylenebis(iminocarbonothioyl)]bis-carbamicacidimethylester;1,2-bis(methoxycarbonylthioureido)benzene;1,2-di-(3-Methoxy-carbonyl-2-thioureido)benzene;4,4’-o-phenylenebis(3-thio-allophanicacidimethylester;bas32500f;caligran;Carbamicacid,[1,2-phenylenebis(iminocarbonothioyl)]bis-,dimethylester
CAS: 23564-05-8
MF: C12H14N4O4S2
MW: 342.39
EINECS: 245-740-7
Product Categories: FUNGICIDE;Alpha sort;MetabolitesPesticides&Metabolites;Q-ZAlphabetic;BenzimidazolesPesticides;CarbamatesEnvironmental Standards;Fungicides;MetabolitesAlphabetic;Pesticides;Pesticides&Metabolites;TF - TO;NULL
Mol File: 23564-05-8.mol
Thiophanate-methyl Structure
 
Thiophanate-methyl Chemical Properties
Melting point  172°C
storage temp.  0-6°C
Water Solubility  <0.1 g/100 mL at 20 ºC
Merck  13,9427
Stability: Stable. Incompatible with strong oxidizing agents, alkalies, copper salts.
EPA Substance Registry System Carbamic acid, [1,2-phenylenebis(iminocarbonothioyl)] bis-, dimethyl ester(23564-05-8)
 
Safety Information
Hazard Codes  Xn;N,N,Xn
Risk Statements  20-43-50/53-68
Safety Statements  36/37-46-60-61
RIDADR  UN 3077
RTECS  BA3675000
Hazardous Substances Data 23564-05-8(Hazardous Substances Data)
MSDS Information
 
Thiophanate-methyl Usage And Synthesis
Description Thiophanate methyl is a member of benzimidazole and a systemic fungicide with protective and curative activity against a broad spectrum of fungal diseases including leaf spots, blotches, blights, fruit spots, rots, sooty mould, scabs, bulb/corn/tuber decays, blossom blights, powdery mildews, certain rusts, and common soil borne crown and root rots. It is used on a variety of tree, vine, root crops, canola, and wheat, as well as on lawns and ornamentals. Thiophanate methyl is absorbed by the roots and leaves. Thiophanate-methyl has a low mammalian toxicity. But, it is an irritant and a skin sensitizer. It may also be mutagen. Moderate toxicity of thiophanate methyl is observed for aquatic organisms and earthworms. In EU, thiophanate methyl is approved to control fungal diseases on crops, while in Australia it is not registered for use on food-producing species, while it is only for the control of soil-borne diseases of ornamentals plants. For application, Thiophanate-methyl is formulated into wettable powders containing 50 and 70% active ingredient.
References
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  5. Terry R Roberts, David H Hutson, Philip W Lee, Peter H Nicholls, and Jack R Plimmer, Metabolic Pathways of Agrochemicals: Part 2: Insecticides and Fungicides, 1999, ISBN 978-0-85404-499-3
Chemical Properties colourless crystals, or white or light brown powder
Uses Thiophanate-Methyl is a systematic fungicide of the thiophanate class. Thiophanate-Methyl is commonly used in agriculture to protect against powdery mildew, rot and other fungal diseases in fruits, ve getables and other crops.
Definition ChEBI: A member of the class of thioureas that is the dimethyl ester of (1,2-phenylenedicarbamothioyl)biscarbamic acid. A fungicide effective against a broad spectrum of diseases in fruit, vegetables, turf and other crops including eyespot, scab, powdery mildew a d grey mould.
Uses Systemic fungicide.
General Description Colorless crystals or light brown powder.
Air & Water Reactions Insoluble in water.
Reactivity Profile Thiophanate-methyl is incompatible with strong acids and bases, and with strong reducing agents such as hydrides. Produces flammable gaseous hydrogen with active metals or nitrides. Incompatible with strong oxidizing acids, peroxides. Incompatible with alkaline material. Forms complexes with copper salts .
Fire Hazard Flash point data for Thiophanate-methyl are not available. Thiophanate-methyl is probably combustible.
 
Thiophanate-methyl Preparation Products And Raw materials
Preparation Products Thiram+Thiophanate-methyl W.P.
Raw materials Methanol-->o-Phenylenediamine-->PHOSGENE-->Sodium thiocyanate-->Methyl chloroformate-->ISOTHIOCYANATE, POLYMER-BOUND, 200-400-->METHYL THIOCYANOFORMATE

 

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