Chlorotris(triphenylphosphine)rhodium(I) Basic information
Reactions
Product Name: Chlorotris(triphenylphosphine)rhodium(I)
Synonyms: DECARBON;CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I);CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODATE (I);TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE POLYMER BOUND;WILKINSON CATALYST
CAS: 14694-95-2
MF: C54H45ClP3Rh
MW: 925.21
EINECS: 238-744-5
Product Categories: Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;metal-phosphine complexes;chemical reaction,pharm,electronic,materials;Rh
Mol File: 14694-95-2.mol
Chlorotris(triphenylphosphine)rhodium(I) Structure
Chlorotris(triphenylphosphine)rhodium(I) Chemical Properties
Melting point 245-250 °C (dec.)
Boiling point >170°C
density 1.363; d 1.379
storage temp. 2-8°C
solubility Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution
form Crystalline Powder
color Red-brown to maroon
Water Solubility insoluble
Sensitive air sensitive
Merck 14,9758
InChIKey QEYYHUJFSQCTAE-UHFFFAOYSA-M
CAS DataBase Reference 14694-95-2(CAS DataBase Reference)
NIST Chemistry Reference chlorotris(triphenylphosphine)rhodium(14694-95-2)
EPA Substance Registry System Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)-(14694-95-2)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-36/38
Safety Statements 22-24/25-37/39-28A-26-15-45-36/37/39
RIDADR 1759
WGK Germany 1
F 8-10-23
TSCA Yes
HS Code 28439090