Phenmedipham 13684-63-4 C16H16N2O4
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Phenmedipham Basic information |
Product Name: | Phenmedipham |
Synonyms: | (3-methylphenyl)-carbamicaci3-((methoxycarbonyl)amino)phenylester;3-(Carbomethoxyamino)phenyl 3-methylcarbanilate;3-(carbomethoxyamino)phenyl3-methylcarbanilate;3-(Methylphenyl)carbamic acid 3-((methoxycarbonyl)amino)phenyl ester;3-(methylphenyl)carbamicacid3-((methoxycarbonyl)amino)phenylester;3-methoxycarbonyl-n-(3’-methylphenyl)-carbamat;3-Methoxycarbonyl-N-(3'-methylphenyl)-carbamat;Beetomax |
CAS: | 13684-63-4 |
MF: | C16H16N2O4 |
MW: | 300.31 |
EINECS: | 237-199-0 |
Product Categories: | CarbanilatePesticides&Metabolites;Alpha sort;Herbicides;N-PAlphabetic;P;PER - POLA;Pesticides&Metabolites |
Mol File: | 13684-63-4.mol |
Phenmedipham Chemical Properties |
Melting point | 140-144°C |
Boiling point | 441.54°C (rough estimate) |
density | 1.1782 (rough estimate) |
refractive index | 1.6240 (estimate) |
Fp | 100 °C |
storage temp. | 0-6°C |
Water Solubility | <0.1 g/100 mL at 21 ºC |
CAS DataBase Reference | 13684-63-4(CAS DataBase Reference) |
NIST Chemistry Reference | Methyl 3-m-tolylcarbamoyloxyphenylcarbamate(13684-63-4) |
EPA Substance Registry System | Carbamic acid, (3-methylphenyl)-, 3-[(methoxycarbonyl)amino] phenyl ester(13684-63-4) |
Safety Information |
Hazard Codes | N |
Risk Statements | 50/53 |
Safety Statements | 60-61 |
RIDADR | UN 3077 |
RTECS | FD9050000 |
Hazardous Substances Data | 13684-63-4(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate | English |
Phenmedipham Usage And Synthesis |
Uses | Phenmedipham is an carbanilate selective herbicide used post-emergence in beet crops after the emergence of most broad-leaved weeds and before they develop. |
Definition | ChEBI: A carbamate ester that is (3-methylphenyl)carbamic acid in which the hydrogen of the hydroxy group has been replaced by a 3-[(methoxycarbonyl)amino]phenyl group. |
Uses | Herbicide. |
General Description | Colorless crystals or white powder. |
Air & Water Reactions | Insoluble in water. |
Reactivity Profile | 3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates. 3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate is incompatible with alkaline preparations. |
Fire Hazard | Flash point data for 3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate are not available, however 3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate is probably combustible. |
Agricultural Uses | Herbicide: A post-emergence herbicide for control of annual broadleaf weeds and grasses in sugar beets, spinach, strawberries, and sunflowers |
Trade name | AIMSAN®; BETAMIX® (phenmedipham + desmedipham); BETANAL®; CQ 1451® (phenmedipham + desmedipham + ethofumesate); EC herbicide (phenmedipham + desmedipham + ethofumesate); EP 452®; KEEPER®; KEMIFAM®; MSS HERBASAN®; NA 305® (phenmedipham + desmedipham + ethofumesate); NA 308® (phenmedipham + desmedipham + ethofumesate); POWERTWIN® (phenmedipham + ethofumesate); PROGRESS® (phenmedipham + desmedipham + ethofumesate); S-4075®; SCHERING 4072®; SN 38584®; SPINAID ®; SYNBETAN-P®; TWIN®; VANGARD® |
Phenmedipham Preparation Products And Raw materials |
Raw materials | N,N-Dimethylaniline-->3-Aminophenol-->Methyl chloroformate-->m-Toluidine-->m-Tolyl isocyanate |
Preparation Products | the BINAP-Rh^<+^> complex |
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