C10H12O2 (S)-(+)-Benzyl glycidyl ether 16495-13-9
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(S)-(+)-Benzyl glycidyl ether 16495-13-9 C10H12O2
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Details:
| (S)-(+)-Benzyl glycidyl ether Basic information |
| Product Name: | (S)-(+)-Benzyl glycidyl ether |
| Synonyms: | (s)-o-benzylglycidol;(S)-(+)-2-(BENZYLOXYMETHYL)OXIRANE;(S)-(+)-1-BENZYLOXY-2,3-EPOXYPROPANE;(S)-1-BENZYLOXY-2,3-EPOXYPROPANE;(S)-(+)-BENZYL GLYCIDYL ETHER;(S)-BENZYL GLYCIDYL ETHER;(S)-BENZYLOXYMETHYL-OXIRANE;(+)-BENZYL (S)-GLYCIDYL ETHER |
| CAS: | 16495-13-9 |
| MF: | C10H12O2 |
| MW: | 164.2 |
| EINECS: | -0 |
| Product Categories: | chiral;CHIRAL COMPOUNDS;Chiral Building Blocks;Glycidyl Compounds, etc. (Chiral);Oxiranes;Simple 3-Membered Ring Compounds;Synthetic Organic Chemistry;Chiral Compound |
| Mol File: | 16495-13-9.mol |
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| (S)-(+)-Benzyl glycidyl ether Chemical Properties |
| Boiling point | 130 °C (0.1 mmHg) |
| alpha | 5.1 º (c=5 in toluene) |
| density | 1.072 g/mL at 20 °C(lit.) |
| refractive index |
n |
| Fp | >110°C |
| storage temp. | 2-8°C |
| BRN | 5246495 |
| CAS DataBase Reference | 16495-13-9(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36-37/39 |
| WGK Germany | 3 |
| RTECS | TX2860030 |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| (S)-(+)-Benzyl glycidyl ether Usage And Synthesis |
| Chemical Properties | Colorless to light yellow liqui |
| Uses | (S)-(+)-Benzyl Glycidyl Ether is used as a reactant in the synthesis of (+)-Discodermolide. |
| Purification Methods | This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.] |
| (S)-(+)-Benzyl glycidyl ether Preparation Products And Raw materials |
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