NICKEL BROMATE Br2N...

NICKEL BROMATE Br2Ni 13462-88-9

NICKEL BROMATE Br2Ni 13462-88-9

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1 Metric Ton

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  • Min.Order :1 Metric Ton
  • Purity: 99.5%
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NICKEL BROMATE 13462-88-9 Br2Ni

Quick Details

  • Appearance:Powder
  • Application: 13462-88-9
  • PackAge:Aluminium Foil Bag and Paper Drum
  • ProductionCapacity:1|Metric Ton|Day
  • Storage:1MT
  • Transportation:By Sea/Air/DHL

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NICKEL BROMATE Basic information
Description References
Product Name: NICKEL BROMATE
Synonyms: NICKEL BROMATE;NiBr2;Nickel bromide (NiBr2);Nickel(II)-bromid;Nickel(II)-bromidwasserfrei;nickelbromide(nibr2);Nickelbromideanhydrousyellowgreenpowder;Nickelbromidehydrateyellowgreenxtl
CAS: 13462-88-9
MF: Br2Ni
MW: 218.5
EINECS: 236-665-0
Product Categories: Crystal Grade Inorganics;Metal and Ceramic Science;Nickel Salts;NickelMetal and Ceramic Science;Salts;Catalysis and Inorganic Chemistry;Chemical Synthesis;metal halide;Crystal Grade Inorganics;Materials Science;Metal and Ceramic Science;Nickel;Nickel Salts;Ni
Mol File: 13462-88-9.mol
NICKEL BROMATE Structure
 
NICKEL BROMATE Chemical Properties
Melting point  963 °C(lit.)
density  5.098 g/mL at 25 °C(lit.)
solubility  H2O: slightly soluble(lit.)
form  powder
color  Brown
Water Solubility  Soluble in water, alcohol and ether.
Sensitive  Hygroscopic
Merck  14,6502
Stability: Stable. Incompatible with strong oxidizing agents.
InChIKey IPLJNQFXJUCRNH-UHFFFAOYSA-L
CAS DataBase Reference 13462-88-9(CAS DataBase Reference)
 
Safety Information
Hazard Codes  T,N,Xi
Risk Statements  45-22-43-50/53-68-48/23-42/43-61-49
Safety Statements  53-36/37-45-60-61
RIDADR  UN 3077 9/PG 3
WGK Germany  3
TSCA  Yes
HazardClass  6.1(b)
PackingGroup  III
MSDS Information
 
 
NICKEL BROMATE Usage And Synthesis
Description Nickel bromide (chemical formula: NiBr2) is the nickel salt of hydrobromic acid. It is a weak reducing agent made by the reaction of nickel, nickel oxide, nickel carbonate or nickel hydroxide with hydrobromic acid, or the reaction between nickel and bromine. Nickel bromide has many kinds of applications. It is mostly an electron acceptor, being capable of catalyze organic structure such as carbonamides, and convert aryl bromides into aryl phosphines. It can also be used as a catalyst in cross-coupling reactions. It is also applied for bonding to other ligands. For example, graphene supported NrBr2 is used in a condensation reaction consisting of aromatic aldehyde, acetoacetate and urea for manufacturing 3, 4- dihydropyrimidiones.
References #(II)_bromide
Chemical Properties Brownish powder
General Description Yellowish-green odorless solid. Sinks in and mixes with water.
Air & Water Reactions Deliquescent. Soluble in water.
Reactivity Profile NICKEL BROMATE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMATE produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMATE emits toxic bromide fumes. [M. K.]
Health Hazard Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.
Fire Hazard Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.
Purification Methods Crystallise it from dilute HBr (0.5mL/g) by partial evaporation in a desiccator. The anhydrous salt is yellow, but the trihydrate is green.

 

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