Acrylyl chloride 814-68-6 99%
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Acrylyl chloride Basic information |
Product Name: | Acrylyl chloride |
Synonyms: | chloridkyselinyakrylove;Propenoyl chloride;propenoylchloride;Acryloyl chloride, stabilized with 400 ppM phenothiazine;Acryloyl chloride, 97%, stabilized with 400 ppm phenothiazine;Acryloyl chloride, 97%, stabilized with 400 ppm p-Hydroxyanisole;Acryloyl chloride, 97%, stabilized with p-Hydroxyanisole;ACRYLOYL CHLORIDE, 96%, STABILIZED |
CAS: | 814-68-6 |
MF: | C3H3ClO |
MW: | 90.51 |
EINECS: | 212-399-0 |
Product Categories: | -;Industrial/Fine Chemicals;Halogen compounds;ACID CHLORIDES |
Mol File: | 814-68-6.mol |
Acrylyl chloride Chemical Properties |
Boiling point | 72-76 °C(lit.) |
density | 1.119 g/mL at 20 °C |
vapor density | >1 (vs air) |
vapor pressure | 1.93 psi ( 20 °C) |
refractive index |
n |
Fp | 61 °F |
storage temp. | 2-8°C |
Water Solubility | Miscible with water. |
Sensitive | Moisture & Light Sensitive |
BRN | 635744 |
Stability: | Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable. |
CAS DataBase Reference | 814-68-6(CAS DataBase Reference) |
NIST Chemistry Reference | 2-Propenoyl chloride(814-68-6) |
EPA Substance Registry System | 2-Propenoyl chloride(814-68-6) |
Safety Information |
Hazard Codes | F,T+ |
Risk Statements | 11-14-26-34 |
Safety Statements | 16-26-28-36/37/39-45-7/9 |
RIDADR | UN 3383 6.1/PG 1 |
WGK Germany | 3 |
RTECS | AT7350000 |
F | 8-10 |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | II |
HS Code | 29161980 |
Hazardous Substances Data | 814-68-6(Hazardous Substances Data) |
Acrylyl chloride Usage And Synthesis |
Chemical Properties | Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator. |
General Description | A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture. |
Air & Water Reactions | Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid. |
Reactivity Profile | Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. |
Fire Hazard | When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water. |
Potential Exposure | May be used as a monomer in preparation of specialty polymers or as a chemical intermediate |
First aid | If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. |
Shipping | UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required |
Incompatibilities | Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals. |
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