trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene Tetraisopropyl methylenediphosphonate ALDRICH
trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene is a funtionalized Diels-Alder diene. Mukaiyama-Michael-type addition/heterocyclization of trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene (Danishefsky?s diene) with 1,2-diaza-1,3-butadiene has been investigated. Asymmetric hetero-Diels-Alder cyclization of Danishefsky?s diene with benzaldehyde catalyzed by mesoporous inorganic/metalorganic hybrid materials has been reported.
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