tert-Butyldimethylsilyl cyanide

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Purity: 97%

Keywords

tert-Butyldimethylsilyl cyanide tert-Butyl-cyano-dimethylsilane ALDRICH

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Appearance:
Application:tert-Butyldimethylsilyl cyanide may be used as reagent for the formation of -isonitrile alcohols via epoxides.
PackAge:1, 10 g in glass bottle
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Superiority:

tert-Butyldimethylsilyl cyanide (TBDMSCN) is a bulkier trialkylsilylcyanide. It participates in the cyanosilylation of enantiopure 4-oxoazetidine-2-carbaldehydes. Addition of TBDMSCN to sterically hindered ketones in the presence of Lewis acid or base catalyst has been studied. ZnI2-catalyzed addition of TBDSCN to 2,2-dimethylcyclohexanone, 2,2,6-trimethylcyclohexanone and 2,2,6,6-tetramethylcyclohexanone affords protected cyanohydrins.

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