CHemwill -- (R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline

 

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
Synonyms:	(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN);(R)-(+)-2-[2-(Diphenylphosphino)Phenyl]-4-(1-Methyl)-4,5-Dihydrooxazole;(4R)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e.;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYL-OXAZOLE;(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;(4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE
CAS:	164858-78-0

 

 

 

Melting point	85-90 °C
alpha	+44° (c 1.4, CHCl3)
form	Powder
color	white
optical activity	[α]20/D +48±3°, c = 1.4% in chloroform
Sensitive	air sensitive
BRN	8156604
InChIKey	OUQSAXROROGQEE-QFIPXVFZSA-N
CAS DataBase Reference	164858-78-0

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	37/39-26-24/25
WGK Germany	3
F	10-23
HS Code	29349990

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

(R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE Usage And Synthesis

Reaction

Chiral ligand used in the asymmetric reduction of highly substituted olefins. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization. Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole. Decarboxylative allylic alkylation.

 

 

 

Chemwill Asia co.,Ltd is one of the leading manufacturer in CHINA. 

 

Our main production base is located in Xuzhou industry park. We produce a wide range of organics including Basic chemicals , Fine chemicals,  Active pharmaceutical ingredients(APIs), Veterinary,  Indole derivatives, Aromatics, Fluorine, Boronic acids, organocatalysts, chiral building blocks, heterocyclic compounds. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place. 

 

Our R&D team masters core technology for process-design of target building block as well as Tailor-made fine chemicals. Our manufactory specialised in extreme temperature conditions (-100ºC to +300ºC), hydrogenations reaction under high pressure, suzuki coupling reaction, photochemical reaction, Mitsunobu reactions, enantioselective reactions and asymmetric synthesis. 

 

Think Chemistry,Think CHemWill

 

 

Factory Plant Address:
High-Tech Industrial park,Chemical Economical Development Zone,Xuzhou, Jiangsu-Province, P.R.China


Shanghai office: (Export Department)
Address: 16FL., INDUSTRY & COMMERCIAL BUILDING, NO.45 YAN’AN ROAD(E), 200002, SHANGHAI, CHINA