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Product Name: | cis-3-Hexenyl hexanoate |
Synonyms: | CIS-HEX-3-ENYL HEXANOATE;CIS-3-HEXENYL HEXANOATE;CIS-3-HEXENYL CAPROATE;CIS-3-HEXEN-1-YL N-HEXANOATE;HEXENYL-CIS-3-CAPROATE;HEXENYL-CIS-3-HEXANOATE;FEMA 3403;C3 HEXENYL CAPROATE |
CAS: | 31501-11-8 |
MF: | C12H22O2 |
MW: | 198.3 |
EINECS: | 250-661-6 |
Product Categories: | -;Alphabetical Listings;Flavors and Fragrances;G-H |
Mol File: | 31501-11-8.mol |
|
cis-3-Hexenyl hexanoate Chemical Properties |
Melting point | 17.88°C (estimate) |
Boiling point | 115 °C15 mm Hg(lit.) |
density | 0.88 g/mL at 25 °C(lit.) |
refractive index |
n |
FEMA | 3403 | CIS-3-HEXENYL HEXANOATE |
Fp | 220 °F |
Specific Gravity | 0.880 |
JECFA Number | 165 |
CAS DataBase Reference | 31501-11-8(CAS DataBase Reference) |
NIST Chemistry Reference | Hexanoic acid, 3-hexenyl ester, (z)-(31501-11-8) |
EPA Substance Registry System | Hexanoic acid, (3Z)-3-hexenyl ester(31501-11-8) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
WGK Germany | 2 |
RTECS | MO8380000 |
HS Code | 29159000 |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
cis-3-Hexenyl hexanoate Usage And Synthesis |
Description | cis-3-Hexenyl hexanoate has a powerful, diffusive fruity-green odor.1 It is reminiscent of pear. May be synthesized by azeotropic esterification of ds-3-hexanol with n-hexanoic acid. |
Chemical Properties | cis-3-Hexenyl hexanoate has a powerful, diffusive fruity-green odor, reminiscent of pear. |
Occurrence | Reported found among the high-boiling components in green tea; also as a component in the volatile fraction of tabasco pepper (Capsicum frutescens). Also reported found in orange peel oil, guava, corn mint oil, passion fruit and juice, plum, plumcot, starfruit, mango, quince, beli (Aegle marmelos Correa), babaco fruit (Carica pentagona Heilborn), nectarine and black choke berry |
Preparation | By azeotropic esterification of cis-3-hexanol with n-hexanoic acid |
Taste threshold values | Taste characteristics at 20 ppm: green, fruity, waxy and sweet with a berry and tropical nuance |
cis-3-Hexenyl hexanoate Preparation Products And Raw materials |
Raw materials | Hexanoic acid-->Hexyl alcohol |
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