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Top rated PROPENYL GUAETHOL(94-86-0) Various Specifications PROPENYL GUAETHOL(94-86-0) PROPENYL GUAETHOL(94-86-0)
Product Name: | PROPENYL GUAETHOL |
Synonyms: | VANITROPE;TRANS-2-ETHOXY-5-(1-PROPENYL)PHENOL;PROPENYL GUAETHOL;2-ETHOXY-5-(1-PROPENYL)PHENOL;2-ETHOXY-5-PROP-1-ENYLPHENOL;2-ETHOXY-5-PROPENYLPHENOL;hydroxymethylanethol;isosafroeugenol |
CAS: | 94-86-0 |
MF: | C11H14O2 |
MW: | 178.23 |
EINECS: | 202-370-0 |
Product Categories: | Alphabetical Listings;Flavors and Fragrances;O-P |
Mol File: | 94-86-0.mol |
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PROPENYL GUAETHOL Chemical Properties |
Melting point | 86-88 °C(lit.) |
Boiling point | 116°C/2mmHg(lit.) |
density | 1.0196 (rough estimate) |
refractive index | 1.5670 (estimate) |
FEMA | 2922 | PROPENYLGUAETHOL |
JECFA Number | 1264 |
CAS DataBase Reference | 94-86-0(CAS DataBase Reference) |
EPA Substance Registry System | Phenol, 2-ethoxy-5-(1-propenyl)-(94-86-0) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-37/39 |
WGK Germany | 2 |
RTECS | SL3850000 |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
PROPENYL GUAETHOL Usage And Synthesis |
Chemical Properties | Free-flowing, white powder; odor and taste similar to vanilla, but much more powerful.Very soluble in fats, edible solvents, and essential oils; very slightly soluble in water. |
Chemical Properties | PROPENYL GUAETHOL exists in (Z)- (mp 35–36°C), [876306-58-0], and in (E)- (mp 86°C), [63477-41-8] forms. The (E)-isomer has a sweet vanilla-like odor. Propenylguethol can be prepared from isosafrole by reaction with methylmagnesium chloride or by ethylation of isoeugenol followed by selective demethylation with alkali . |
Chemical Properties | Propenylguaethol has a vanilla-like odor and flavor. |
Uses | Artificial vanilla flavoring, flavor enhancer. |
Preparation | By alkaline hydrolysis of 1-ethoxy-2-methoxy-4-propenyl benzene in ethanol or methanol solution at 150 to 190°C under pressure; or in ethylene glycol solution at the same temperature under atmospheric pressure; by saponification and contemporary transposition of the double bond starting from 1-ethoxy-2-methoxy-4-allyl benzene. |
Aroma threshold values | Detection: 400 ppb. Aroma characteristics at 1.0%: vanilla, sweet, spicy, slightly phenolic with a heliotropine- like creaminess. |
Taste threshold values | Taste characteristics at 25 ppm: vanilla, spicy, sweet nutty, anisic with a biting creaminess. |
PROPENYL GUAETHOL Preparation Products And Raw materials |
Preparation Products | Ethyl vanillin |
Raw materials | Allylbenzene |
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