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Product Name: | Bis(methylthio)methane |
Synonyms: | 2,4-DITHIAPENTANE;FEMA 3878;FORMALDEHYDE DIMETHYL MERCAPTAL;DIMETHYLTHIOMETHANE;BIS(METHYLMERCAPTO)METHANE;BIS(METHYLTHIO)METHANE;METHYLENEBIS(METHYL SULFIDE);Bis(methylsulfanyl)methane |
CAS: | 1618-26-4 |
MF: | C3H8S2 |
MW: | 108.23 |
EINECS: | 216-577-9 |
Product Categories: | -;Industrial/Fine Chemicals;sulfide Flavor;Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds |
Mol File: | 1618-26-4.mol |
|
Bis(methylthio)methane Chemical Properties |
Melting point | 148 °C |
Boiling point | 147 °C(lit.) |
density | 1.059 g/mL at 25 °C(lit.) |
refractive index |
n |
FEMA | 3878 | BIS-(METHYLTHIO)METHANE |
Fp | 111 °F |
storage temp. | Flammables area |
solubility | IMMISCIBLE |
form | neat |
Specific Gravity | 1.059 |
color | APHA: ≤100 |
Water Solubility | IMMISCIBLE |
Merck | 14,1256 |
JECFA Number | 533 |
BRN | 1731143 |
CAS DataBase Reference | 1618-26-4(CAS DataBase Reference) |
NIST Chemistry Reference | 2,4-Dithiapentane(1618-26-4) |
EPA Substance Registry System | Methane, bis(methylthio)-(1618-26-4) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 10-36/37/38 |
Safety Statements | 16-26-36/37/39 |
RIDADR | UN 1993 3/PG 3 |
WGK Germany | 3 |
F | 13 |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | III |
HS Code | 29309070 |
MSDS Information |
Provider | Language |
---|---|
2,4-Dithiapentane | English |
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Bis(methylthio)methane Usage And Synthesis |
Chemical Properties | CLEAR COLOURLESS TO PALE YELLOW LIQUID |
Chemical Properties | bis-(Methylthio)methane has a mustard-like odor. |
Occurrence | Reported found in Camembert and Gruyere cheeses, milk, fish oil, cooked and canned beef, shitake mushroom, truffle, prawn and lobster. |
Purification Methods | Work in an efficient fume cupboard as the substance may contain traces (or more) of methylmercaptan which has a very bad odour. Dissolve the mercaptal in Et2O, shake it with aqueous alkalis then dry it over anhydrous K2CO3, filter and distil it over K2CO3 under a stream of N2. If the odour is very strong, then allow all gas efluents to bubble through 5% aqueous NaOH solution which is then treated with dilute KMnO4 in order to oxidise MeSH to odourless products. UV: max 238 nm (log 2.73) [Fehnel & Carmack J Am Chem Soc 71 90 1949, Fehér & Vogelbruch Chem Ber 91 996 1958, B.hme & Marz Chem Ber 74 1672 1941]. Oxidation with aqueous KMnO4 yields bis-(methylsulfonyl)methane which has m 142-143o [Fiecchi et al. Tetrahedron Lett 1681 1967]. [Beilstein 1 IV 3088.] |
Bis(methylthio)methane Preparation Products And Raw materials |
Preparation Products | Methyl 2-(methylamino)benzoate |
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