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Product Name: | 3-(Methylthio)butanal |
Synonyms: | 3-(METHYLMERCAPTO)BUTYRALDEHYDE;3-(METHYLTHIO)BUTANAL;3-METHYLTHIO BUTYLALDEHYDE;3-(METHYLTHIO)BUTYRALDEHYDE;FEMA 3374;3-(METHYLTHIO)BUTANAL 96+%;3-(Methylyhio)Butanal;Butanal, 3-(methylthio)- |
CAS: | 16630-52-7 |
MF: | C5H10OS |
MW: | 118.2 |
EINECS: | 240-678-7 |
Product Categories: | sulfide Flavor;Alphabetical Listings;Flavors and Fragrances;M-N |
Mol File: | 16630-52-7.mol |
|
3-(Methylthio)butanal Chemical Properties |
Boiling point | 62-64 °C10 mm Hg(lit.) |
density | 1.001 g/mL at 25 °C(lit.) |
vapor density | 4.1 (vs air) |
vapor pressure | 60 mm Hg ( 20 °C) |
refractive index |
n |
FEMA | 3374 | 3-(METHYLTHIO)BUTANAL |
Fp | 144 °F |
Sensitive | Air Sensitive |
JECFA Number | 467 |
CAS DataBase Reference | 16630-52-7(CAS DataBase Reference) |
EPA Substance Registry System | Butanal, 3-(methylthio)-(16630-52-7) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | 1989 |
WGK Germany | 3 |
TSCA | Yes |
HS Code | 29309090 |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
ALFA | English |
3-(Methylthio)butanal Usage And Synthesis |
Description | 3-(Methylthio)butanal has the flavor of potato chips. It is prepared by addition of methanethiol to the corresponding unsaturated aldehyde (previously cooled to -20°C), using piperidine or copper acetate as catalyst; by a patented oxo process. |
Chemical Properties | 3-Methylthiobutyraldehyde has a green, musky, buchu odor and a flavor reminiscent of potato chip |
Occurrence | Reported found in French fried potato and krill. |
Preparation | By addition of methanethiol to the corresponding unsaturated aldehyde (previously cooled to -20°C), using piperidine or copper acetate as catalyst; by a patented oxo process |
Taste threshold values | Taste characteristics at 0.2 ppm: vegetative, tomato, fishy and sulfureous. |
3-(Methylthio)butanal Preparation Products And Raw materials |
Raw materials | Cupric acetate monohydrate -->METHYL MERCAPTAN-->Crotonaldehyde-->Cupric acetate |
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