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Tetrahydrothiophen-3-one 3-Oxotetrahydrothiophene 3(2H)-Thiophenone,dihydro-
Product Name: | Tetrahydrothiophen-3-one |
Synonyms: | 3-Oxotetrahydrothiophene;3-Thiacyclopentanone;dihydro-3(2h)-thiophenon;Dihydro-3-Thiophenone;Thiolan-3-one;4,5-DIHYDRO-3(2H)-THIOPHENONE;3-THIOPHANONE;dihydrothiophen-3(2h)-one |
CAS: | 1003-04-9 |
MF: | C4H6OS |
MW: | 102.15 |
EINECS: | 213-698-9 |
Product Categories: | -;Thiophene&Benzothiophene;thiophene Flavor;Thiophen flavors |
Mol File: | 1003-04-9.mol |
|
Tetrahydrothiophen-3-one Chemical Properties |
Boiling point | 175 °C(lit.) |
density | 1.194 g/mL at 25 °C(lit.) |
vapor density | >1 (vs air) |
refractive index |
n |
FEMA | 3266 | 4,5-DIHYDRO-3(2H)THIOPHENONE |
Fp | 171 °F |
storage temp. | 2-8°C |
form | Liquid |
color | Colorless to pale yellow |
Specific Gravity | 1.194 |
JECFA Number | 498 |
BRN | 105201 |
CAS DataBase Reference | 1003-04-9(CAS DataBase Reference) |
NIST Chemistry Reference | Dihydro-3-(2H)-thiophenone(1003-04-9) |
EPA Substance Registry System | 3(2H)-Thiophenone, dihydro- (1003-04-9) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36-36/37/39 |
RIDADR | UN 3334 |
WGK Germany | 3 |
F | 8-13 |
Hazard Note | Irritant |
TSCA | Yes |
HS Code | 29349990 |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
ALFA | English |
Tetrahydrothiophen-3-one Usage And Synthesis |
Description |
Tetrahydro-thiophene-3-one is a heterocyclic nonaromatic ketone. It has a garlic meaty, green vegetable, buttery odor. It is present in cooked beef, coffee, roast filbert, and roasted peanut. Tetrahydro-thiophene-3-one is used as a food flavoring agent. It is also a valuable organic substance key that opens the synthetic access to numerous derivatives of thiophene. |
Chemical Properties | 4,5-Dihydro-3-(2H)thiophenone has a garlic meaty, green vegetable, buttery odor. It is a heterocyclic nonaromatic ketone. |
Chemical Properties | Clear light yellow liquid |
Occurrence | Reported found in cooked beef, coffee, roasted filberts and roasted peanuts. |
Uses | Used for blending soft drinks, beverage, meat products, confectionery, and milk product flavors. |
Preparation | From 4-methoxycarboxyl-3-oxothiophane treated with 10% sulfuric acid. |
Taste threshold values | Taste characteristics at 15 ppm: onion, garlic, cooked meaty with vegetables nuances |
References |
[1] George A. Burdock (2010) Fenaroli's Handbook of Flavor Ingredients, Sixth Edition [2] # [3] Patent 0127121 A1: Process for the preparation of tetrahydro-thiophen-3-one |
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