CasNo.546-68-9,Titanium tetraisopropanolateCAS NO.: 546-68-9,(546-68-9) Suppliers

1 Kilogram	FOB Price:USD 4.0000 -5.0000

Min.Order :1 Kilogram
Purity: 99%
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Keywords

Titanium tetraisopropanolate TTIP 99.5% Titanium tetraisopropanolate

Quick Details

Appearance:colourless liquid
Application:Catalyst and Auxiliary
PackAge:Aluminium Foil Bag and Paper Drum
ProductionCapacity:10000|Gram|Day
Storage:Room temperature
Transportation:By sea or by air

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Details:

Hazard Codes	Xi,F
Risk Statements	10-36-36/37/38-11-67
Safety Statements	16-26-36/37/39-7/9
RIDADR	UN 2413 3/PG 3
WGK Germany	2
RTECS	NT8060000
F	21
TSCA	Yes
HazardClass	3
PackingGroup	III
HS Code	29051900
Hazardous Substances Data	546-68-9(Hazardous Substances Data)

MSDS Information

Provider	Language
Titanium(IV) isopropoxide	English
ACROS	English
SigmaAldrich	English
ALFA	English

Titanium tetraisopropanolate Usage And Synthesis

Reactions	Catalyst for the synthesis of acyclic epoxy alcohols and allylic epoxy alcohols. Useful for diastereoselective reduction of alpha-fluoroketones. Catalyzes the asymmetric allylation of ketones. Reagent for the synthesis of cyclopropylamines from aryl and alkenyl nitriles. Useful for racemic and/or enantioselective addition of nucleophiles to aldehydes, ketones and imines. Catalytic intramolecular formal [3+2] cycloaddition. Catalyst for the synthesis of cyclopropanols from esters and organomagnesium reagents
Chemical Properties	colourless to light yellow liquid
Uses	Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.
General Description	A water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water and . Flash point 66°F. Vapors heavier than air.
Air & Water Reactions	Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.
Reactivity Profile	Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.
Health Hazard	Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Purification Methods	Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]