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Hexahydrophthalic anhydride 1,2-Cyclohexanedicarboxylic Acid anhydride 1,3-Isobenzofurandione, hexahydro-
Description | Hexahydrophthalic anhydride (HHPA) is widely used for electronics applications, e.g. HHPA cured epoxy resins have excellent dielectric properties, high-temperature stability, and high glass transition temperatures. HHPA is used as a curing agent in adhesive coatings and sealant materials, e.g. for the second-generation two-part epoxy adhesive synthesis. Hexahydrophthalic anhydride is also used in the manufacture of alkyd and polyester resins, insecticides, and rust preventives. |
References |
[1] Guy Rabilloud, High Performance Polymers. Vol. 1 Conductive Adhesives, 1997 [2] John Burke Sullivan and Gary R. Krieger, Clinical Environmental Health and Toxic Exposures, 2001 [3] B. A. G. Jönsson, H. Welinder, C. Hansson and B. Ståhlbom, Occupational exposure to hexahydrophthalic anhydride: air analysis, percutaneous absorption, and biological monitoring, International Archives of Occupational and Environmental Health 1993, vol. 65, 43-47 |
Chemical Properties | White crystalline powder |
Uses | Intermediate for alkyds, plasticizers, insect repellents, and rust inhibitors; hardener in epoxy resins. |
Definition | ChEBI: A cyclic dicarboxylic anhydride that is the cyclic anhydride of hexahydrophthalic acid. |
Hazard | Toxic by inhalation, strong irritant to eyes and skin. |
Purification Methods | It has been obtained by heating the trans-acid or anhydride at 200o. Crystallise it from *C6H6/Et2O or distil it. [Kohler & Jansen J Am Chem Soc 60 2145 1938, Abell J Org Chem 22 769 1957, Beilstein 17 II 452, 17 III/IV 5931.] |
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