Ammonium metavanadate

Min.Order / FOB Price:Get Latest Price

25 Kilogram	Negotiable

25 Kilogram

Negotiable

Min.Order :25 Kilogram
Purity: 99%
Payment Terms : L/C,D/A,D/P,T/T,,MoneyGram,Other

Keywords

Ammonium metavanadate 7803-55-6 H4NO3V

Quick Details

Appearance:White to yellow solid
Application:raw material
PackAge:As required
ProductionCapacity:5|Metric Ton|Month
Storage:Dry and cold condition
Transportation:by sea or by air

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Ammonium metavanadate Basic information

Description References

Product Name:	Ammonium metavanadate
Synonyms:	vanadicacid,ammoniumsalt;AMMONIUM METAVANADATE;AMMONIUM M-VANADATE;AMMONIUM MONOVANADATE;AMMONIUM OXIDE;AMMONIUM VANADATE;AMMONIUM VANADATE(+5);AMMONIUM VANADATE, META
CAS:	7803-55-6
MF:	H4NO3V
MW:	116.98
EINECS:	232-261-3
Product Categories:	Industrial/Fine Chemicals;Inorganics;ACS GradeChemical Synthesis;Catalysis and Inorganic Chemistry;Essential Chemicals;Routine Reagents;Vanadium;A-B, Puriss p.a. ACS;Analytical Reagents for General Use;Puriss p.a. ACS;Ammonium SaltsChemical Synthesis;Metal and Ceramic Science;Salts;Ammonium Salts;-;Chemical Synthesis;A-B, Puriss p.a.;Puriss p.a.;inorganic compound
Mol File:	7803-55-6.mol

Ammonium metavanadate Chemical Properties

Melting point	200 °C
density	2.32 g/cm³ at 25 °C(lit.)
storage temp.	Store at RT.
solubility	H₂O: soluble
form	Solid
color	White to yellow
Specific Gravity	2.33
PH	7 (5.1g/l, H2O, 20℃)
Water Solubility	5.1 g/L (20 ºC)
Merck	14,568
Stability:	Stable. Incompatible with strong acids, strong oxidizing agents. Protect from moisture - hygroscopic.
CAS DataBase Reference	7803-55-6(CAS DataBase Reference)
EPA Substance Registry System	Ammonium vanadate (7803-55-6)

Safety Information

Hazard Codes	T+,T
Risk Statements	25-26-36/37/38-20-34-22-36/37-23/24/25
Safety Statements	26-36/37/39-45-37/39-22-28
RIDADR	UN 2859 6.1/PG 2
WGK Germany	3
RTECS	YW0875000
F	3
TSCA	Yes
HazardClass	6.1
PackingGroup	II
HS Code	28419030
Hazardous Substances Data	7803-55-6(Hazardous Substances Data)
Toxicity	LD50 orally in rats: 0.16 g/kg (Smyth)

Ammonium metavanadate Usage And Synthesis

Description	Ammonium metavanadate can be used as a catalyst for organic synthesis. Thermal decomposition of ammonium metavanadate yields vanadium pentoxide, V205, which is widely used as catalyst and precursor for other vanadium compounds and metallic vanadium itself. Ammonium metavanadate is a reagent in the analytical chemistry and a developer in the photography industry. Ammonium metavanadate is used in dyeing and printing in the textile industry. Ammonium metavanadate is also used as dryer for paints.
References	[1] Kirti S.Niralwad, Bapurao B.Shingate and Murlidhar S.Shingare, Microwave-assisted one-pot synthesis of octahydroquinazolinone derivatives using ammonium metavanadate under solvent-free condition, Tetrahedron Letters, 2010, vol. 51, 3616-3618 [2] Ganesh R. Jadhav, Mohammad U. Shaikh, Rajesh P. Kale, Charansingh H. Gill, Ammonium metavanadate: A novel catalyst for synthesis of 2-substituted benzimidazole derivatives, Chinese Chemical Letters, 2009, vol. 20, 292-295 [3] Swapnil S. Sonar, Amol H. Kategaonkar, M. N. Ware; Charansingh H. Gill, Bapurao B. Shingate and Murlidhar S. Shingare, Ammonium metavanadate: an effective catalyst for synthesis of α-hydroxyphosphonates, ARKIVOC, 2009, vol. 2009, 138-148 [4] Klaus-Jürgen Range and Reinhard Zintl, The thermal decomposition of ammonium metavanadate (V) in open and closed systems, Zeitschrift für Naturforschung B, 1988, vol.43, 309-317 [5] Jeanne Mager Stellman, Encyclopaedia of Occupational Health and Safety: Chemical, Industries and Safety, 2012 [6] NPCS Board of Consultants & Engineers, Selected Formulary Book on Inks, Paints, Lacquers, Varnishes and Enamels, 2007
Chemical Properties	white or slightly yellow powder or crystals
Chemical Properties	Ammonium metavanadate is a white or slightly yellow crystalline powder. It is an inorganic acidic salt
Uses	Used in combustion analysis of carbon, hydrogen, and nitrogen
Uses	In dyeing and printing on woolens; staining wood black; manufacture of vanadium black and "indelible ink"; producing vanadium luster on pottery; as photographic developer; in hematoxylin staining in microscopy; as reagent in analytical chemistry.
General Description	A white crystalline powder. Slightly soluble in water and denser than water. Decomposes at 410°F. May release toxic fumes. Moderately toxic. An irritant. Used as a dryer for paints and inks, and for dyes. Loses ammonia upon heating.
Air & Water Reactions	Slightly soluble in water.
Reactivity Profile	Acidic inorganic salts, such as Ammonium metavanadate, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Health Hazard	TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard	Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Safety Profile	Poison by ingestion, subcutaneous, intravenous, intratracheal, and intraperitoneal routes. Moderately toxic by skin contact. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. See also VANADIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of NH3, VOx, and NOx.
Potential Exposure	It is used in the metals industry to make alloys, chemical reactions, dyes, inks, varnishes, printing, medicines, and photography.
Shipping	UN2859 Ammonium metavanadate, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Purification Methods	Wash the salt with H2O until free from Cl-ions and dry it in air. It is soluble in H2O (5.18g/100mL at 15o, 10.4g/100mL at 32o) but is more soluble in dilute NH3. It crystallises from conductivity water (20mL/g). When heated at relatively low temperature, it loses H2O and NH3 to give vanadium oxide (V2O5), and at 210o it forms lower oxides. [Baker et al. Inorg Synth III 117 1950.] Its solubility in H2O is 0.52% (15o), 1% (32o) and 1.6% (50o). After washing the technical grade salt with H2O, it had Na, Mn and U at 0.06, 0.2 and 0.1 ppm, respectively. [Brauer in Handbook of Preparative Inorganic Chem (Ed. Brauer) Academic Press Vol II p 1272-1273 1965.]
Incompatibilities	Moisture forms an acidic solution. React with bases and alkaline material: may generate heat and release flammable hydrogen gas.

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