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1-Amino-3-methoxybenzene m-anisidien 3-Methoxy-1-aminobenzene
Chemical Properties | Light yellow liquid. |
Chemical Properties | Anisidine exists as ortho-, meta-, and paraisomers. They have characteristic amine (fishy) odors. |
Uses | m-Anisidine is a highly poisonous monosubstituted aniline used as corrosion inhibitorsfor aluminum, copper and other metals in acidic solutions. |
General Description | Pale yellow oily liquid or dark red liquid. |
Air & Water Reactions | m-Anisidine may be sensitive to prolonged exposure to air and light. Insoluble in water. |
Reactivity Profile | m-Anisidine is incompatible with strong oxidizers. m-Anisidine is also incompatible with acids, acid chlorides, acid anhydrides and chloroformates. |
Fire Hazard | m-Anisidine is probably combustible. |
Safety Profile | Moderately toxic by ingestion.Mutation data reported. When heated to decomposition itemits toxic vapors of NOx. |
Potential Exposure | Anisidines are used in the manufacture of azo dyes; pharmaceuticals; textile-processing chemicals Incompatibilities: Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine,bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some coatings and some forms of plastic and rubber. |
Shipping | UN2431 Anisidines, Hazard Class: 6.1; Labels: 6.1-Poisonous materials |
Purification Methods | o-Isomer impurity can be removed by steam distillation. Another possible impurity is the precursor 3-nitroanisole which can be removed as for the preceding o-isomer and fractionating using an efficient column. It is a yellow liquid. [Gilman & Kyle J Am Chem Soc 74 3027 1952, Bryson J Am Chem Soc 82 4858 1960, Kadaba & Massie J Org Chem 22 333 1957, Beilstein 13 IV 953.] |
Waste Disposal | Dissolve in combustible solvent (alcohols, benzene, etc.) and spray solution into furnace equipped with afterburner and scrubber, or burn spill residue on sand and soda ash absorbent in a furnace. |
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