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2,2′-bis(diphenylphosphino)-1,1′-binaphthyl BINAP 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl BINAP
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1.1'-Binaphthyl-2.2'-diphemyl phosphine Basic information
Product Name: 1.1'-Binaphthyl-2.2'-diphemyl phosphine
Synonyms: (+/-)-(1,1'-BINAPHTHALENE-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE);(+/-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL;2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL;(+/-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENE;Racemic-2,2’-bis(diphenylphosphino)-1,1’-binaphthy;RACEMIC-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL BINAP;RAC-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL / RAC-BINAP;2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl (Racemic BINAP)
CAS: 98327-87-8
MF: C44H32P2
MW: 622.67
EINECS: 619-338-0
1.1'-Binaphthyl-2.2'-diphemyl phosphine Chemical Properties
Melting point 283-286 °C(lit.)
Boiling point 724.3±55.0 °C(Predicted)
form Powder
color White to light beige
Water Solubility Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.
Sensitive Air Sensitive
1.1'-Binaphthyl-2.2'-diphemyl phosphine Usage And Synthesis
Chemical Properties 1.1'-Binaphthyl-2.2'-diphemyl phosphine is White to light beige powder
Uses
racemic-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl ( (+/-)-BINAP ) is an essential role in the organic synthesis of enantioselective transformations catalyzed by the complexes of ruthenium, rhodium and palladium.
It is also employed in palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines.
used with Cu(II) to catalyze the addition of arylsulfonamides to styrenes and olefins.
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